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碱性介质中卤素离子引起铁腐蚀的差异及腐蚀抑制
引用本文:牛林,陈晓. 碱性介质中卤素离子引起铁腐蚀的差异及腐蚀抑制[J]. 山东大学学报(理学版), 1996, 0(2)
作者姓名:牛林  陈晓
作者单位:Dept. of Chem.,Shaloforlg Univ.,Jinan
基金项目:中科院金属腐蚀与防护国家重点实验室与化学院青年基金
摘    要:用电化学方法研究了卤素离子引起铁腐蚀的差异.解释了Cl-、Br-、I-引起铁孔蚀的顺序,发现F-对铁阳极过程的影响明显不同于其它卤素离子.通过络合效应和沉淀效应解释了F-和EDTA对铁孔蚀的抑制作用.

关 键 词:铁;卤素离子;孔蚀;腐蚀抑制作用

THE DIFFERENCES OF CORROSION CAUSED BY HALIDE IONS ON IRON IN ALKALINE MEDIA AND THE CORROSION INHIBITION
Niu Lin, Chen Xiao. THE DIFFERENCES OF CORROSION CAUSED BY HALIDE IONS ON IRON IN ALKALINE MEDIA AND THE CORROSION INHIBITION[J]. Journal of Shandong University, 1996, 0(2)
Authors:Niu Lin   Chen Xiao
Abstract:The differences of corrosion caused by halide ions on iron in alkaline media were studied by electrochemical metheds. The order of pitting corrosion caused by Clx,Br and I- on iron has been interpreted. It was found that the influence of F- on the anodic process of iron was remarkably different from that of other halide ions. The pitting corrosion inhibiting action of F- and EDTA was interpreted by complexing and precipitating effects.
Keywords:iron  halide ions  pitting corrosion  corrosion inhibiting action
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