| Synthesis,Structural Characterization,and Electrochemical Properties of Binuclear Copper(Ⅱ) Complexes Containing Tetradentate Schiff Base Ligand |
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| 基金项目： | Supported by the Project for Distinguished Young Scholars from Hubei Provincial Department of Education (Q20082601) |
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| 摘 要： | Two binuclear copper(Ⅱ) complexes, [Cu2(saloph)2 (μ-O)2]-2(DMF)[H2saloph=N,N′-o-phenylenebis(salicylideneaminato)] (a) and [Cu2(salen)2(μ-O)2] [H2salen=N,N′-bis(salicylic-deneaminato) ethylene] (b)were synthesized and characterized by X-ray crystallography. Both of them have distorted rectangular pyramidal geometry around Cu(Ⅱ). The complete series of complexes show bridging phenoxo groups between the copper centers, together with hydroxo-bridges in these complexes. The complexes have also been characterized by elemental analysis, IR, TG-DTA, and electrochemical results.
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| 关 键 词： | copper(Ⅱ) complexes crystal structure electrochemical properties |
Synthesis,structural characterization,and electrochemical properties of binuclear copper(II) complexes containing tetradentate Schiff base ligand |
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| Yu Ding,Xiaoxia Hu,Xiaoli Sun,Zhiling Zuo. Synthesis,structural characterization,and electrochemical properties of binuclear copper(II) complexes containing tetradentate Schiff base ligand[J]. Wuhan University Journal of Natural Sciences, 2010, 15(2): 165-170. DOI: 10.1007/s11859-010-0215-8 |
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| Authors: | Yu Ding Xiaoxia Hu Xiaoli Sun Zhiling Zuo |
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| Affiliation: | DING Yu,HU Xiaoxia,SUN Xiaoli,ZUO Zhiling School of Chemistry , Materials Science,Xiaogan University,Xiaogan 432000,Hubei,China |
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| Abstract: | Two binuclear copper (II) complexes, [Cu2(saloph)2(μ-O)2]·2(DMF)[H2saloph=N,N′-o-phenylenebis(salicylideneaminato)](a) and [Cu2(salen)2(μ-O)2] [H2salen=N,N′-bis(salicylic-deneaminato) ethylene] (b)were synthesized and characterized by X-ray crystallography. Both of them have distorted rectangular pyramidal geometry around Cu(II). The complete series of complexes show bridging phenoxo groups between the copper centers, together with hydroxo-bridges in these complexes. The complexes have also been characterized by elemental analysis, IR, TG-DTA, and electrochemical results. |
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