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| 金属胶束模拟辣根过氧化物酶催化过氧化氢氧化苯酚 | |
| 引用本文： | 黄忠,谢家庆,冯发美,蒋炳英,胡常伟,曾宪诚.金属胶束模拟辣根过氧化物酶催化过氧化氢氧化苯酚[J].四川大学学报(自然科学版),2003,40(6):1137-1142. |
| 作者姓名： | 黄忠 谢家庆 冯发美 蒋炳英 胡常伟 曾宪诚 |
| 作者单位： | 1. 四川大学化学学院,成都610064;中国工程物理研究院化工材料研究所,四川绵阳,621900 2. 四川大学化学学院,成都610064;四川理工学院化学系,四川自贡,643000 3. 四川大学化学学院,成都610064 |
| 基金项目： | 国家自然科学基金资助项目( 20173038,20107004);四川理工学院课题资助 |
| 摘 要： | 研究了咪唑衍生物钴配合物Co(biap)·Cl2和胶束形成的金属胶束作为模拟辣根过氧化物酶(HRP)催化H2O2氧化苯酚反应;探讨了过氧化氢浓度、反应温度、酸度和胶束性质影响催化反应的原因;提出了金属胶束催化氧化苯酚的反应历程;建立了金属胶束催化苯酚氧化的动力学数学模型. |
| 关 键 词： | 咪唑衍生物Co（Ⅱ）配合物 金属胶束 模拟辣根过氧化物酶 |
| 文章编号： | 0490-6756(2003)06-1137-06 |
The Metallomicelle as Mimetic Horseradish Peroxidase were Used in the Catalytic Oxidation of Phenol by H2O2 |
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| HUANG Zhong.The Metallomicelle as Mimetic Horseradish Peroxidase were Used in the Catalytic Oxidation of Phenol by H2O2[J].Journal of Sichuan University (Natural Science Edition),2003,40(6):1137-1142. | |
| Authors: | HUANG Zhong |
| Institution: | HUANG Zhong~ |
| Abstract: | The oxidation of phenol by H_(2)O_(2)was studied in the paper used the metallomicelle made of the complexes of imidazole groups and micelle as the mimetic peroxidase instead of Horseradish peroxidase; the cause that catalytic effects were changed with H_(2)O_(2)],temperature, pH, andmicelles on the catalytic reactionwas analyzed; the mechanism of the catalytic reaction was discussed; the kinetic mathematic model on the phenol oxidation catalyzed by the metallomicelles was proposed. |
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