| FTIR法研究环氧树脂/超支化聚合物共混体系固化反应 |
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| 引用本文： | 陈建芳,张海良,刘敏娜,王霞瑜. FTIR法研究环氧树脂/超支化聚合物共混体系固化反应[J]. 湘潭大学自然科学学报, 2004, 26(3): 72-76 |
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| 作者姓名： | 陈建芳 张海良 刘敏娜 王霞瑜 |
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| 作者单位： | 1. 湘潭大学,高分子材料研究所,湖南,湘潭,411105;湖南工程学院,化工系,湖南,湘潭,411104
2. 湘潭大学,高分子材料研究所,湖南,湘潭,411105 |
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| 基金项目： | 湖南省青年科学基金资助项目(02B007) |
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| 摘 要： | 通过傅立叶红外光谱在位跟踪法，研究了环氧树脂／超支化聚合物共混体系在以4，4′-二氨基二苯砜为固化剂时的固化行为，讨论了固化反应特征，研究了固化温度，超支化聚合物(HBP)含量对共混体系的固化反应程度的影响，并根据Arrhenius公式得出其体系固化反应的表观活化能，结果表明，HBP对EP与DDS的固化反应具明显促进作用，并降低了固化反应的表观活化能。
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| 关 键 词： | FTIR法 环氧树脂 超支化聚合物 固化反应 |
| 文章编号： | 1000-5900(2004)03-0072-05 |
| 修稿时间： | 2003-12-11 |
Study on The Curing Reaction of Epoxy Resin/Hyperbranched Ploymer Blends System By FTIR |
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| CHEN Jianfang. Study on The Curing Reaction of Epoxy Resin/Hyperbranched Ploymer Blends System By FTIR[J]. Natural Science Journal of Xiangtan University, 2004, 26(3): 72-76 |
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| Authors: | CHEN Jianfang |
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| Affiliation: | CHEN Jianfang~ |
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| Abstract: | By Fourier FTIR spectra,curing behavior of epoxy /hyperbranched polymer blends system,using 4,4'diamino-diphenyl sulphohe as curing agent was researhed and the curing mechanism was confirmed.Curing temperature,the content of hyperbranched polymer's influnce on the curing reaction of blends system and the apparent activation energy of curing reaction in the blends system according to Arrherious equation were obtained. |
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| Keywords: | FTIR epoxy resin hyperbranched polymer curing reaction |
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