| 硝酸铕(Ⅲ)与邻香兰素二胺类双希夫碱配合物的研究 |
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| 引用本文： | 赵国良,李彬,焦庆祝.硝酸铕(Ⅲ)与邻香兰素二胺类双希夫碱配合物的研究[J].高师理科学刊,1991(2). |
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| 作者姓名： | 赵国良 李彬 焦庆祝 |
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| 作者单位： | 浙江师范大学
(赵国良)，吉林大学
(李彬)，齐齐哈尔师范学院化学系(焦庆祝) |
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| 摘 要： | 本文首次合成了邻香兰素(3-甲氧基-2-羟基苯甲醛)与乙二胺、联苯胺、邻苯二胺、间苯二胺、对苯二胺缩合而成的双希夫碱(分别用L~1,L~2,L~3,L~4,L~5表示)的硝酸铕(Ⅲ)配合物,对它们进行了元素分析、摩尔电导、红外光谱、X射线光电子能谱测定,确定了组成,推断了结构,并研究了它们的热稳定性和发光特性。
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| 关 键 词： | 铕(Ⅲ)配合物 邻香兰素 双希夫碱 |
Studies on the Complexes of Europium (Ⅲ) Nitrate with Bis-schiff Bases Derived from o-Vanillin and Some Diamines |
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| Zhao Guoliang Li Bin Jiao Qingzhu.Studies on the Complexes of Europium (Ⅲ) Nitrate with Bis-schiff Bases Derived from o-Vanillin and Some Diamines[J].Journal of Science of Teachers＇College and University,1991(2). |
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| Authors: | Zhao Guoliang Li Bin Jiao Qingzhu |
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| Institution: | Zhao Guoliang Li Bin Jiao Qingzhu
(Zhejiang Normal University)
(Jilin University)
(Department of Chemistry) |
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| Abstract: | The complexes of Europium(Ⅲ)nitrate with bis-schiff bases derived from o-vaniilin and ethylene-diamine, benzidine, o-phenylenediamine, m-phenylenediamine,p-phenylenediamine(indicated as L1, L2, L3, L4, L5, respectively) have been synthesized for the first time.The compositions and proposed structures are studied with the measurements of elemental analysis, molar conductance,infrared spectra,x-ray photoelectron spectra.Their thermal stabilities and luminescence properties are also studied. |
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| Keywords: | Europium(Ⅲ)complex O-vanillin Bis-schiff base |
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