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液相反应速度常数扩散极限值的计算和用途
引用本文:袁伟. 液相反应速度常数扩散极限值的计算和用途[J]. 北京化工大学学报(自然科学版), 1990, 0(3)
作者姓名:袁伟
作者单位:北京化工学院应用化学系
摘    要:系统地介绍了稀溶液中反应速度常数扩散极限值的推导和计算法,并用实例说明了它在判断实验数据和机理假设的合理性以及在实验设计方面的应用。

关 键 词:液相  反应  反应速度  扩散  动力学  限制

Calculation and Application of Diffusion-Limited Rate Constants in Solutions
Yuan Wei. Calculation and Application of Diffusion-Limited Rate Constants in Solutions[J]. Journal of Beijing University of Chemical Technology, 1990, 0(3)
Authors:Yuan Wei
Affiliation:Department of Applied Chemistry
Abstract:The deduction process of the diffusion-limited kinetics was systematically and concisedy illustrated both for steady and non-steady states. Though the assumptions used for evaluating the diffusion-limted rate constants were plausible, their estimated values could still find some applications in the aspects of testing experimental da ta, judging the reaction mechanismas well as designing experiments.
Keywords:liquid phase   reaction   rate   diffusion   kinetics.
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