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三硝基甲苯(TNT)废水连续光催化降解分析
引用本文:刘学梅,;邓洪权,;蒋琪英.三硝基甲苯(TNT)废水连续光催化降解分析[J].西南科技大学学报,2014(4):24-28.
作者姓名:刘学梅  ;邓洪权  ;蒋琪英
作者单位:[1]西南科技大学材料科学与工程学院,四川绵阳621010; [2]西南科技大学教育部生物质工程中心,四川绵阳621010
基金项目:过程装备与控制工程四川省重点实验室基金(GK201002)
摘    要:在自制的列管式光催化器中,以纳米Ti O2P25为光催化剂,对三硝基甲苯(TNT)废水连续光催化降解条件进行实验研究。结果表明,反应管连接方式及列管数目、流体流量、催化剂用量、H2O2的添加以及光照条件等均对TNT废水的光降解存在不同程度的影响。4根管子采用串联方式,气体流量3 L/min,液体流量0.5 L/h,同时添加27 mmol/L H2O2时,TNT废液(20 mg/L)可彻底矿化。

关 键 词:TNT  光催化  光降解  光反应器

Analysis of Continuous Photocatalytic Degradation of Trinitrotoluene
Institution:LIU Xue - mei, DENG Hong - quan , JIANG Qi - ying (1. School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China ; 2. Engineering Research Center of Biomass Materials, Ministry of Education, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China)
Abstract:Main affecting factors on the degradation of trinitrotoluene (TNT) wastewater, such as the number of reaction tubes, connection mode, liquid and air flow, catalyst dosage, amount of H2O2 and intensity of illumination, were discussed in a self - made tubular array reactor, with the Deggusa P25 TiO2 as the photocatalyst. The results show all those factors like the number of tubes, their connection mode, fluid flow, dosage of catalyst, addition of H2O2 and light condition, etc, affect the degradati wastewater to some extent. The most suitable conditions for the degradation of TNT solution (20 clucle four tubes connected end to end, the liquid and gas flow rate of 0.5 L/h ,the gas flow L/min, and the mount of 27 mmol/L of H2O2.
Keywords:TNT  Photo - catalysis  Photo - degradation  Photoreactor on of TNT mg/L) in- rate of 3  0
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