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Spectroscopic study on the photophysical properties of chlorine substituted tetraphenylporphyrin-histidine and its zinc(Ⅱ)complexes
作者姓名:ZHANG Huijuan  FENG Juan  AI Xicheng  ZHANG Xingkang  YU Zhongheng & ZHANG Jianping State Key Laboratory for Structural Chemistry of Unstable and StableSpecies   Center of Molecular Science  Institute of Chemistry  Chinese Academy of Sciences  Beijing 100080  China
作者单位:ZHANG Huijuan,FENG Juan,AI Xicheng,ZHANG Xingkang,YU Zhongheng & ZHANG Jianping State Key Laboratory for Structural Chemistry of Unstable and StableSpecies; Center of Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China
摘    要:As the structural analogues of (bacterio)chlorophylls in photosynthetic organisms, porphyrins play an important role in building up artificial photosynthetic systems[13]. In natural photosynthetic pigment-protein complexes,certain amino acid residuals modulate the reactions ofcharge transfer and energy transfer via coordination andother types of interactions with chlorophyll molecules.For instance, in higher-plant photosynthetic reaction cen-ter PSⅡ, the oxidization-reduction system consistin…

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