| 利用Wittig反应合成荧光增白剂DX.EB |
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| 引用本文： | 冯艳辉,张坤斌.利用Wittig反应合成荧光增白剂DX.EB[J].高师理科学刊,2006,26(3):59-61. |
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| 作者姓名： | 冯艳辉 张坤斌 |
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| 作者单位： | 1. 大庆华科股份有限公司,黑龙江,大庆,163316
2. 大庆石油管理局,黑龙江,大庆,163000 |
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| 摘 要： | 基于Wittig反应原理,利用(邻氰基苄基)膦酸二甲酯、(对氰基苄基)膦酸二甲酯、对苯二甲醛和甲醇钠合成了荧光增白剂DX.EB,研究了合成工艺.当原料(邻氰基苄基)膦酸二甲酯∶(对氰基苄基)膦酸二甲酯=1∶1.5,40℃滴加甲醇钠时,收率为最佳,可达74.72%.
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| 关 键 词： | Wittig反应 荧光增白剂DX.EB 合成 |
| 文章编号： | 1007-9831(2006)03-0059-03 |
| 修稿时间： | 2006年1月6日 |
Synthesis of fluorescent brightener DX.EB based on Wittig reaction |
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| FENG Yan-hui,ZHANG Kun-bin.Synthesis of fluorescent brightener DX.EB based on Wittig reaction[J].Journal of Science of Teachers＇College and University,2006,26(3):59-61. |
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| Authors: | FENG Yan-hui ZHANG Kun-bin |
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| Abstract: | Based on the Wittig reaction principle,fluorescent whiter DX.EB was synthesized from 2-nitril-benzyl-dimethyl-phosphatidate(1),4-nitril-benzyl-dimethyl-phosphatidate(2),terephthalalic aldehyde and methyl sodium.The synthetic technology of DX.EB was studied.The synthetic technology of DX.EB was studied.The yield was 74.72% at n(1): n(2) = 1: 1.5,dropped methyl sodium at 40℃. |
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| Keywords: | Wittig reaction fluorescent brightener DX EB synthesis |
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