| 简单一级化学反应热动力学数据处理的新方法 |
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| 引用本文： | 李可群. 简单一级化学反应热动力学数据处理的新方法[J]. 实验室科学, 2011, 14(5): 76-77,82. DOI: 10.3969/j.issn.1672-4305.2011.05.023 |
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| 作者姓名： | 李可群 |
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| 作者单位： | 同济大学化学系,上海,200092 |
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| 摘 要： | 提出一种处理简单一级反应热动力学实验数据的简便方法。该方法无需测定热谱曲线最大峰高或反应完全时的峰高,而使用热谱曲线峰高自然对数值对时间曲线的近似直线部分来同时获取反应速率常数和体系冷却常数。
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| 关 键 词： | 热动力学 一级反应 热谱 速率常数 冷却常数 |
A new data treatment method for thermokinetics of first-order chemical reaction |
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| LI Ke-qun. A new data treatment method for thermokinetics of first-order chemical reaction[J]. Laboratory Science, 2011, 14(5): 76-77,82. DOI: 10.3969/j.issn.1672-4305.2011.05.023 |
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| Authors: | LI Ke-qun |
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| Affiliation: | LI Ke-qun(Department of Chemistry,Tongji University,Shanghai 20092,China) |
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| Abstract: | A new simple method was presented to treat the thermokinetic experimental data of first-order chemical reaction.This method can simultaneously determine rate constants and cooling constants by using the approximate linear sections of logarithmic values of height of thermogram against times other than determining peak height or curve height at the end of chemical reaction. |
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| Keywords: | thermokinetics first-order chemical reaction thermogram rate constant cooling constant |
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