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A New Type of Dibenzoyl Tartaric Acid Selective Electrode Based on Polymer Membrane Containing Calixarene Ionophore
引用本文:Meng L ing|zhi,Mei Gong|xiong,He Yong|bing,Li Jiang|feng (College of Chemistry and Molecular Sciences,Wuhan University,Wuhan,430072,Hubei,China). A New Type of Dibenzoyl Tartaric Acid Selective Electrode Based on Polymer Membrane Containing Calixarene Ionophore[J]. 武汉大学学报:自然科学英文版, 2003, 0(1)
作者姓名:Meng L ing|zhi  Mei Gong|xiong  He Yong|bing  Li Jiang|feng (College of Chemistry and Molecular Sciences  Wuhan University  Wuhan  430072  Hubei  China)
作者单位:College of Chemistry and Molecular Sciences,Wuhan University,Wuhan,430072,Hubei,China
基金项目:SupportedbyNationalNaturalScienceFoundationofChina(2 0 0 72 0 2 9)
摘    要:0 IntroductionCalixarenesandtheirderivativeshaveattractedgreatinterestinhost guestchemistry .Theyarenotedfortheirabilitytoformhost guestcomplexesbytrappingorganiccompounds,smallions ,andgasesintheirtoruslikecavitiesaswellastomimicenzymefunctions[1] .Theyca…


A New Type of Dibenzoyl Tartaric Acid Selective Electrode Based on Polymer Membrane Containing Calixarene Ionophore
Meng L ing|zhi,Mei Gong|xiong,He Yong|bing,Li Jiang|feng. A New Type of Dibenzoyl Tartaric Acid Selective Electrode Based on Polymer Membrane Containing Calixarene Ionophore[J]. Wuhan University Journal of Natural Sciences, 2003, 0(1)
Authors:Meng L ing|zhi  Mei Gong|xiong  He Yong|bing  Li Jiang|feng
Abstract:A new type of di benzoyl tartaric acid selective electr ode has been developed. Three double| arm calixarene derivatives were emp loyed as the neutral ionophores. The poly(vinyl chloride) membrane electrode containing an amide derivative of ca lixarene as the neutral carrier an d a dibutyl phthalate as the plastici zer exhibited the highest sensitivity for dibenzoyl tartaric acid. The slop e of linear portion was 27.8 mV per c oncertration decade. The electrode has a fast response and a long lifetime .
Keywords:ion|selective electrode  calixarene ionophore  mole cular recognition  dibenzoyl tartaric acid
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