具有核壳结构的金属有机框架纳米材料的研究进展

多组分无机纳米粒子(NPs)和金属有机框架(MOFs)的可控一体化,正在引领着多种新型多功能材料的形成.具有核壳结构的金属有机框架纳米粒子(NP@MOF),综合了多组分无机纳米粒子和金属有机框架(MOFs)协同性质,NP@MOF材料的突出优点是:它的组成具有无限选择性、壳上孔径具有可调性、核壳具有多功能性,这种突出的独特功能使得人们争相洞察其未来发展.主要综述了具有核壳结构的多组分金属有机框架纳米粒子的制备方法和研究进展,最后介绍了其在多相催化、气体存储等方面的应用.

Research progress of metal-organic framework nanomaterials with core-shell structure

Controllable integration of multicomponent inorganic nanoparticles (NPs) and metal-organic frameworks (MOFs) is leading to the creation of many new multifunctional materials.Metal-organic framework nanomaterials with core-shell structure possess synergy effect of inorganic NPs and MOFs for multifunctional applications.The outstanding advantages of NP@MOF,such as limitless selection of composition,tunable pore sizes of the shells,and multifunctional cores and shells,provide insight into their future development.The recent advances in the preparation of coordination polymer nanomaterials are reviewed.At last,the research progress in their applications in gas storage/separation and catalysis are introduced.