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新型中和缓蚀剂对常减压塔顶H2S-HCl-H2O腐蚀作用的影响
引用本文:杨敬一,陈伟军,徐心茹,杨仁海. 新型中和缓蚀剂对常减压塔顶H2S-HCl-H2O腐蚀作用的影响[J]. 华东理工大学学报(自然科学版), 2005, 31(4): 429-432
作者姓名:杨敬一  陈伟军  徐心茹  杨仁海
作者单位:华东理工大学石油加工研究所,上海,200237;中国石化镇海炼油化工股份有限公司,镇海,315200
摘    要:研究了新型中和缓蚀剂SF-121B和BZH-1在常减压蒸馏塔顶H2S-HCl-H2O腐蚀系统中的缓蚀效果,结果表明随着H2S浓度增加,腐蚀速率增加;温度升高,溶液pH值下降,腐蚀增加.中和缓蚀剂SF-121B和BZH-1的缓蚀效果优于目前工业常用的7019.SF-121B与氨水复配在保持较好缓蚀效果的同时,可减少操作成本.

关 键 词:腐蚀  碳钢  H2S  缓蚀剂  有机胺
文章编号:1006-3080(2005)04-0429-04
修稿时间:2004-08-19

Influence of New Neutralizing Corrosion Inhibitors on H2S-HCl-H2O System on the Top of Atmospheric and Vacuum Distillation Tower
YANG Jing-yi,CHEN Wei-jun,XU Xin-ru,YANG Ren-hai. Influence of New Neutralizing Corrosion Inhibitors on H2S-HCl-H2O System on the Top of Atmospheric and Vacuum Distillation Tower[J]. Journal of East China University of Science and Technology, 2005, 31(4): 429-432
Authors:YANG Jing-yi  CHEN Wei-jun  XU Xin-ru  YANG Ren-hai
Affiliation:YANG Jing-yi~1*,CHEN Wei-jun2,XU Xin-ru1,YANG Ren-hai2
Abstract:The effect of new neutralizing corrosion inhibitors, SF-121B and BZH-1, for inhibiting carbon steel corrosion in H_2S-HCl-H_2O system on the top of atmospheric and vacuum distillation tower was studied. The result indicated that with the H_2S concentration increasing, the corrosion rate increased. With the temperature increasing, the pH value of solution decreased and the corrosion rate increased. Neutralizing corrosion inhibitors, SF-121B and BZH-1, which had more excellent inhibited corrosion than the corrosion inhibitor 7019. The mixture of SF-121B and ammonia not only had excellent inhibited corrosion but also reduced operation cost.
Keywords:corrosion  carbon steel  H_2S  corrosion inhibitor  organic amine
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