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Mica-stabilized polyethylene glycol composite phase change materials for thermal energy storage
作者姓名:Dongyao Zhang  Chuanchang Li  Niangzhi Lin  Baoshan Xie  Jian Chen
作者单位:School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410114, China
基金项目:This work was financially supported by the National Nat-ural Science Foundation of China(Nos.51874047 and 51504041);the Special Fund for the Construction of Innovat-ive Provinces in Hunan Province,China(No.2020RC3038);the Changsha City Fund for Distinguished and Innovative Young Scholars,China(No.kq1802007);the Fund for Uni-versity Young Core Instructors of Hunan Province,China,the Innovation Program for Postgraduate of Changsha Uni-versity of Science and Technology,China;the Outstand-ing Youth Project of Hunan Provincial Department of Educa-tion,China(No.18B148).
摘    要:Mica was used as a supporting matrix for composite phase change materials(PCMs)in this work because of its distinctive morphology and structure.Composite PCMs were prepared using the vacuum impregnation method,in which mica served as the supporting material and polyethylene glycol(PEG)served as the PCM.Fourier transform infrared and X-ray diffraction analysis confirmed that the addition of PEG had no effect on the crystal structure of mica.Moreover,no chemical reaction occurred between PEG and mica during the vacuum impregnation process,and no new substance was formed.The maximum load of mica-stabilized PEG was 46.24%,the phase change temperature of M400/PEG was 46.03℃,and the latent heat values of melting and cooling were 77.75 and 77.73 J·g?1,respectively.The thermal conductivity of M400/PEG was 2.4 times that of pure PEG.The thermal infrared images indicated that the thermal response of M400/PEG improved relative to that of pure PEG.The leakage test confirmed that mica could stabilize PEG and that M400/PEG had great form-stabilized property.These results demonstrate that M400/PEG has potential in the field of building energy conservation.

关 键 词:MICA  polyethylene  glycol  phase  change  materials  thermal  energy  storage

Mica-stabilized polyethylene glycol composite phase change materials for thermal energy storage
Dongyao Zhang,Chuanchang Li,Niangzhi Lin,Baoshan Xie,Jian Chen.Mica-stabilized polyethylene glycol composite phase change materials for thermal energy storage[J].International Journal of Minerals,Metallurgy and Materials,2022,1(1):168-176.
Authors:Zhang Dongyao  Li Chuanchang  Lin Niangzhi  Xie Baoshan  Chen Jian
Abstract:Mica was used as a supporting matrix for composite phase change materials (PCMs) in this work because of its distinctive morphology and structure. Composite PCMs were prepared using the vacuum impregnation method, in which mica served as the supporting material and polyethylene glycol (PEG) served as the PCM. Fourier transform infrared and X-ray diffraction analysis confirmed that the addition of PEG had no effect on the crystal structure of mica. Moreover, no chemical reaction occurred between PEG and mica during the vacuum impregnation process, and no new substance was formed. The maximum load of mica-stabilized PEG was 46.24%, the phase change temperature of M400/PEG was 46.03°C, and the latent heat values of melting and cooling were 77.75 and 77.73 J·g?1, respectively. The thermal conductivity of M400/PEG was 2.4 times that of pure PEG. The thermal infrared images indicated that the thermal response of M400/PEG improved relative to that of pure PEG. The leakage test confirmed that mica could stabilize PEG and that M400/PEG had great form-stabilized property. These results demonstrate that M400/PEG has potential in the field of building energy conservation.
Keywords:mica  polyethylene glycol  phase change materials  thermal energy storage
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