| 电子几率分布与六配位配合物构型的畸变方式 |
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| 引用本文： | 王静之,邵军,张琪.电子几率分布与六配位配合物构型的畸变方式[J].聊城大学学报(自然科学版),1997(2). |
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| 作者姓名： | 王静之 邵军 张琪 |
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| 作者单位： | 菏泽医专化学系 |
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| 摘 要： | 在晶体场理论的基础上，根据简并轨道上电子的等几率分布原理和d轨道的角度分布特征，探讨了六配位配合物主要向拉长八面体畸变的物理原因。
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| 关 键 词： | 晶体场理论 等几率分布原理 John—Teller效应 构型畸变 |
THE CONFIQURATIONAL DISTORTED MODESOF TRANSITION METAL SIX-LIGAND COORDINATION COMPOUNDS |
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| Wang Jingzhi, Shao Jun Zhang Qi.THE CONFIQURATIONAL DISTORTED MODESOF TRANSITION METAL SIX-LIGAND COORDINATION COMPOUNDS[J].Journal of Liaocheng University:Natural Science Edition,1997(2). |
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| Authors: | Wang Jingzhi Shao Jun Zhang Qi |
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| Institution: | Heze Medical College |
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| Abstract: | In this paper, the reason why six-ligand coordination compounds are mostly dis-torted to clongated Octnhedral was discussed,which based on the crytal field theory andthe angle distribution characteristics of dorbital. |
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| Keywords: | Crystal field theory Equal probability distribution theory John-Tellereffect Distortion |
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