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水中硝基苯的超声降解处理研究
引用本文:谢娟,屈撑囤,张琴. 水中硝基苯的超声降解处理研究[J]. 西安石油大学学报(自然科学版), 2009, 24(3)
作者姓名:谢娟  屈撑囤  张琴
作者单位:1. 西安石油大学,化学化工学院,陕西,西安,710065;陕西省油气田环境污染控制技术与储层保护重点实验室
2. 北京理工大学,化工与环境学院,北京,100081
基金项目:陕西省科学技术研究发展计划 
摘    要:通过正交实验确定影响超声波降解硝基苯的因素,探讨了在超声条件下反应温度、超声频率、处理时间对硝基苯降解的影响;并对超声/H2O2、超声/H2O2/CuO体系对硝基苯的降解效果进行了初步研究.结果表明:在超声条件下,当硝基苯初始质量浓度为150.8mg/L、超声频率为40kHz、作用时间为6h时,硝基苯的降解率为18%;在超声/H2O2条件下,H2O2投加量为3.0mL时,降解率可提高至22.3%;向超声/H2O2体系中加入CuO可使硝基苯的降解率提高到38.7%.

关 键 词:硝基苯  降解  超声波联合技术  正交实验

Study on the degradation of nitrobenzene in aqueous solution by ultrasonic technology
XIE Juan,QU Cheng-tun,ZHANG Qin. Study on the degradation of nitrobenzene in aqueous solution by ultrasonic technology[J]. Journal of Xian Shiyou University, 2009, 24(3)
Authors:XIE Juan  QU Cheng-tun  ZHANG Qin
Abstract:The factors of influencing the degradation rate of the nitrobenzene contained in wastewater such as reaction temperature,ultrasonic frequency and treating time are studied through orthogonal experiments.The effects of ultrasound/H2O2 and ultrasound/H2O2 /CuO on the degradation of nitrobenzene are also investigated.The results show that when the initial concentration of nitrobenzene is 150.8 mg/L,ultrasonic frequency is 40 kHz,treating time is 6 h,the degradation rate of nitrobenzene reaches 18% by using ultrasound alone,it can be increase to 22.3% under ultrasonic/H2O2 when the dosing quantity of H2O2 is 3.0 mL,and it can be increased to 38.7% when CuO is added to the ultrasonic/H2O2 system.
Keywords:nitrobenzene  degradation  ultrasonic joint technique  orthogonal experiment
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