| 碘化钇与15-冠-5,18-冠-6配合物的合成及其性质 |
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| 引用本文： | 胡安全,谭民裕,翟应离,甘新民.碘化钇与15-冠-5,18-冠-6配合物的合成及其性质[J].中南大学学报(自然科学版),1989(3). |
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| 作者姓名： | 胡安全 谭民裕 翟应离 甘新民 |
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| 作者单位： | 中南工业大学，中南工业大学，兰州大学，兰州大学 |
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| 摘 要： | 分别从已腈和乙醚(1:1)及乙醇和乙醚(1:10)混和溶剂为介质制得了碘化钇与15-冠-5(15 C 5),18-钇-6(18 C 6)的组成为1:1(钇:冠醚)的混和物,所得配合物在高真空时稳定,置于空气中缓慢被氧化而分解。通过元素分析、摩尔电导、红外、差热-热重和X射线粉末衍射等分析该段研究了它们的有关性质,得到了一些新结果。
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| 关 键 词： | 稀土元素 配合物 冠醚配合物 光谱分析 热分析 X射线衍射分析 |
SYNTHESIZING COMPLEXES OF YTTRIUM IODIDE WITH 15-CROWN-5 AND WITH 18-CROWN-6 AND THEIR PROPERTIES |
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| Hu Anquan.SYNTHESIZING COMPLEXES OF YTTRIUM IODIDE WITH 15-CROWN-5 AND WITH 18-CROWN-6 AND THEIR PROPERTIES[J].Journal of Central South University:Science and Technology,1989(3). |
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| Authors: | Hu Anquan |
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| Institution: | Hu Anquan (Central-South University of Technology)
Tan Minyu;Zhai Yingli;Gan Xinmin (Lanzhou University) |
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| Abstract: | Complexes of yttrium iodide with 15-crown-5 and with 18-crown-6, with a stoichiometry of 1: 1, have been synthesized by using acetonitrile: ether (1: 1) and ethanol: ether (1: 10) as solvent respectively. These isolated complexes are rela- tively stable under high vaccum but will decompose in atmosphere. Their proper- ties have been investigated by means of IR spectrum, stability and molar conductance, thermogravimetric and differential thermal analysis and X-ray diffraction. |
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| Keywords: | rare earth element complex compound crown ether compound spectrum analysis thermal analysis X-ray diffraction analysis |
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