| 混合电解质溶液中活度系数的MSA计算 |
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| 引用本文： | 王风云. 混合电解质溶液中活度系数的MSA计算[J]. 南京理工大学学报(自然科学版), 1991, 0(1) |
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| 作者姓名： | 王风云 |
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| 作者单位： | 化工学院 |
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| 摘 要： | 本文根据MSA方法,计算了在一系列不同浓度的LiCl、NaCl、KCl和CsCl水溶液中HCl的平均活度系数,计算结果与文献实验值吻合得较好。文末还对计算结果及影响结果的因素进行了简要讨论。
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| 关 键 词： | 电解质 水溶液 活度系数 计算 MSA方法 |
Prediction of Activity Coefficient in Aqueous Electrolyte Mixtures Using the Mean Sphere Approximation |
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| Wang Fengyun Chemical Engineering School. Prediction of Activity Coefficient in Aqueous Electrolyte Mixtures Using the Mean Sphere Approximation[J]. Journal of Nanjing University of Science and Technology(Nature Science), 1991, 0(1) |
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| Authors: | Wang Fengyun Chemical Engineering School |
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| Affiliation: | Wang Fengyun Chemical Engineering School |
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| Abstract: | Mean activity coefficients of 0. 01 m HCl in the HCl-LiCl,HCl-NaCl,HCl-KCl and HCl-CsCl aqueous solutions have been computed at 298 Kover a wide range of MCl (M = Li, Na, K, Cs) concentration by use of themean sphere approximation (MSA). The results are in good agreement withthose from literature. A brief discussion about the factors affecting the resultswas given at the end of the article. |
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| Keywords: | electrolyte aqueous solution activity coefficient computation MSA method |
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