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| 一种新方法合成吡嗪甲酸根合铜(Ⅱ)配合物 | |
| 引用本文： | 夏道成,姚纪欢,夏到鹏,刘立峰,白青龙,王厅厅,马建方.一种新方法合成吡嗪甲酸根合铜(Ⅱ)配合物[J].山西大学学报(自然科学版),2010,33(1). |
| 作者姓名： | 夏道成 姚纪欢 夏到鹏 刘立峰 白青龙 王厅厅 马建方 |
| 作者单位： | 1. 运城学院化学系,山西运城044000;东北师范大学化学学院,吉林长春130024 2. 运城学院化学系,山西运城,044000 3. 吉林永吉四中,吉林永吉,132200 4. 吉林永吉实验高中,吉林永吉,132200 5. 大连理工大学物理与光电工程学院,辽宁大连,116023 6. 东北师范大学化学学院,吉林长春,130024 |
| 摘 要： | 文章介绍了一种合成二水吡嗪甲酸合铜配合物Cu(CPY)_2(H_2O)_2](CPY=吡嗪-2-甲酸根)的新方法,用吡嗪二甲酸为起始原料与二水乙酸合铜反应得到二水吡嗪甲酸合铜配合物,合成了以吡嗪-2-甲酸根为配体的单核铜(II)配合物Cu(CPY)_2(H_2O)_2].对该配合物进行了元素分析表征,并对其进行了X-射线单晶结构测定.该单晶属于单斜晶系,空间群为P 2(1)/c,其晶胞参数为α=5.4447(11)(A)、alpha=90 deg;b=10.894(2)(A)、beta=98.23(3)deg、c=10.386(2)(A);gamma=90 deg,Volume=609.7(2)(A)3. |
| 关 键 词： | 合成 晶体结构 配合物 吡嗪甲酸 |
A Novel Method for Synthesized Copper (II) Complex Generated from Pyrazine-2-Carboxylate Ligand |
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| XIA Dao-cheng,YAO Ji-huan,XIA Dao-peng,LIU Li-feng,BAI Qing-long,WANG Ting-ting,MA Jian-fang.A Novel Method for Synthesized Copper (II) Complex Generated from Pyrazine-2-Carboxylate Ligand[J].Journal of Shanxi University (Natural Science Edition),2010,33(1). | |
| Authors: | XIA Dao-cheng YAO Ji-huan XIA Dao-peng LIU Li-feng BAI Qing-long WANG Ting-ting MA Jian-fang |
| Institution: | XIA Dao-cheng1,2,YAO Ji-huan1,XIA Dao-peng3,LIU Li-feng4,BAI Qing-long5,WANG Ting-ting1,MA Jian-fang2(1.College of Chemistry,Yuncheng Univercity,Yuncheng 044000,China,2.Faculty of Chemistry,Northeast Normal University,Changchun 130024,3.Yongji Experimental Second Middle School,Yongji 132200,4.Yongji Fourth Middle School,5.School of Physics , Optoelectronic Technology,Dalian University of Technology,Dalian 116023,China) |
| Abstract: | Abstraet:A novel method for synthesized copper (II) complex generated from pyrazine-2-carboxylate ligand is presented. The mononuclear complexCu (CPY)_2(H_2O)_2] (CPY= pyrazine -2-carboxylate anion)with pyrazine-2-carboxylate and H_2O as ligands was synthesized by Pyrazine-2, 3-dicarboxylic acid and Cu (AcO)_2. 2H_2O as starting materials at first time. The complex was characterized through elemental analysis and its crystal structure determined with X-ray crystallography. The crystal belongs to monoclinic system, space group P2(1) / c with α=5.4447(11) (A),alpha=90 deg;b=10. 894(2) (A), beta=98.23(3) deg,c=10. 386(2) (A) ;gamma=90 deg, Volume 609.7(2) (A)3. |
| Keywords: | synthesis crystal structure complex pyrazinecarboxylic acid |
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