| 紫外激光诱导Mn2（CO）10的气相光解离沉积动力学 |
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| 引用本文： | 张振满,许坚.紫外激光诱导Mn2（CO）10的气相光解离沉积动力学[J].复旦学报(自然科学版),1997,36(1):21-26. |
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| 作者姓名： | 张振满 许坚 |
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| 作者单位： | 复旦大学物理二系!上海，200433 |
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| 摘 要： | 采用石英晶体微量秤技术研究了紫外激光诱导的Ｍｎ２（ＣＯ）１０气相光解离沉积反应，发现Ｎｎ２（ＣＯ）１０气相母体分子浓度，激光能量密度与光解离沉积速度均呈线性关系。
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| 关 键 词： | 气相光解离沉积 十羰基二锰 激光诱导 动力学 |
Gaseous photodissociation deposition kinetics of UV laser-induced Mn_2 (CO)_(10) |
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| Zhang Zhenman, Xu Jian, Hou Huiqi.Gaseous photodissociation deposition kinetics of UV laser-induced Mn_2 (CO)_(10)[J].Journal of Fudan University(Natural Science),1997,36(1):21-26. |
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| Authors: | Zhang Zhenman Xu Jian Hou Huiqi |
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| Institution: | Institute of Laser Chemistry |
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| Abstract: | Using QCM technique,the kinetics of gaseous photodissociation deposition of Mn2 (CO)10 induced by 337. 1 nm laser is studied. The linear dependence of the photodissociation deposition rate on the laser intensity and on the number of original Mn2 (CO)10 molecule in gaseous phase have been obtained,which conform to rules of gaseous molecule single-photo dissociation rate equation. The gaseous molecule single-photo dissociation is the rate-determining course in the UV laser-induced Mn2 (CO)10 photodissociation deposition. Mn2 (CO)10 photodissociates into carbonyl maganese with lower number of corrdinate and deposites on the surface of gold plated quartz crystal. |
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| Keywords: | UV laser gaseous photodissociation deposition decacarbonyl-dimaganese maganese compounds |
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