| 新型三嗪类氮杂环蕃的合成与表征 |
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| 引用本文： | 花成文,董鑫,潘然,苟小锋,李小安,赵军龙.新型三嗪类氮杂环蕃的合成与表征[J].西北大学学报,2012(2):231-235. |
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| 作者姓名： | 花成文 董鑫 潘然 苟小锋 李小安 赵军龙 |
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| 作者单位： | 西北大学 合成与天然功能分子化学教育部重点实验室/化学与材料科学学院 |
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| 基金项目： | 西安市科技计划基金资助项目(CXY1123(3)) |
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| 摘 要： | 目的探索三嗪类氮杂环蕃的结构。方法以三聚氯氰、丙氨酸、十二醇、1,6-己二胺、对苯二胺、4,4’-二氨基-二苯醚、4,4’-二氨基-二苯甲烷为原料,经过酯化、取代反应来合成,并通过IR,1HNMR,MALDI-TOFMS和元素分析对其结构进行表征。结果合成了三种新型三嗪类氮杂环蕃。结论该类型三嗪环蕃有特殊的内空腔及外围结构,为其在分子识别,进而在人工模拟酶、催化剂等方面的应用奠定了基础。
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| 关 键 词： | 三聚氯氰 氮杂环蕃 合成 表征 |
Synthesis and characterization of new azacyclophanes of 1,3,5-triazine |
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| HUA Cheng-wen,DONG Xin,PAN Ran,GOU Xiao-feng, LI Xiao-an,ZHAO Jun-long.Synthesis and characterization of new azacyclophanes of 1,3,5-triazine[J].Journal of Northwest University(Natural Science Edition),2012(2):231-235. |
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| Authors: | HUA Cheng-wen DONG Xin PAN Ran GOU Xiao-feng LI Xiao-an ZHAO Jun-long |
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| Institution: | (Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science,Northwest University,Xi′an 710069,China) |
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| Abstract: | Aim To explore the structure of Azacyclophanes of 1,3,5-Triazine.Methods The target products were synthesized from Cyanuric chloride,Alanine,Dodecanol,1,6-diamine,P-phenylenediamine,4,4’-diamino-ether,4,4,-diamino-diphenyl methane by esterification and substitution,and their structures were characterized by 1H NMR,IR,MALDI-TOF-MS techniques and elemental analysis.Results Three novel Azacyclophanes of 1,3,5-Triazine were synthesized.Conclusion Azacyclophanes of 1,3,5-Triazine of this type have a special cavity structure,which lays the foundation for molecular relognition and then in artificial enzymes,catalysts and other aspects of the application. |
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| Keywords: | cyanuric chloride azacyclophane synthesis characterization |
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