| 离子交换树脂支载的镍、钴、铜金属硼化物催化剂的研究 |
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| 引用本文： | 覃彩芹,陈家威. 离子交换树脂支载的镍、钴、铜金属硼化物催化剂的研究[J]. 湖北大学学报(自然科学版), 1994, 0(4) |
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| 作者姓名： | 覃彩芹 陈家威 |
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| 摘 要： | 采用聚合物还原剂硼氢阴离子交换树脂（ＢＥＲ）与镍、钴和铜的醋酸盐分别反应制备聚合物支载的金属硼化物催化剂：ＰＰ一２Ｃｕ、ＰＰ－２Ｃｏ和ＰＰ－２Ｎｉ。并以硼氢化钠为还原剂，探讨该种催化剂在碳碳双键、芳香硝基、氰基及辽氮重健等功能基化合物的还原中的作用。
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| 关 键 词： | 聚合物支载催化剂，硼氢化钠，金属硼化物，还原 |
THE Ni.Co AND Cu METAL BORIDE CATALYSTS SUPPORTED BY ION EXCHANGE RESIN |
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| Qin Caiqin,Chen Jiawei. THE Ni.Co AND Cu METAL BORIDE CATALYSTS SUPPORTED BY ION EXCHANGE RESIN[J]. Journal of Hubei University(Natural Science Edition), 1994, 0(4) |
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| Authors: | Qin Caiqin Chen Jiawei |
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| Affiliation: | Department of chemistry |
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| Abstract: | The resin- supported metal borides,i.e.Cupric boride,Cobalt boride and Nickel boride which can catalyze the reduction of arylnitro.nitrile.diazo and C =C double bonds compounds with sodium borohydride solution,have been prepared by borohydride anion exchange resin reaction with cupric .cobalt and nickel acetates in ethanol. |
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| Keywords: | Polymer -supported catalyst lon exchange resin Metal boride Reduction |
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