| 对液固色谱保留值方程的系统考察 |
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| 引用本文： | 吴也平,张维冰,彭丽萍. 对液固色谱保留值方程的系统考察[J]. 高师理科学刊, 1994, 0(1) |
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| 作者姓名： | 吴也平 张维冰 彭丽萍 |
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| 作者单位： | 齐齐哈尔轻工学院(吴也平，张维冰)，黑龙江省分析测试中心(彭丽萍) |
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| 摘 要： | 本文对目前已有的几种典型的液固色谱保留值方程加以综述,并采用统计热力学的方法,从色谱热力学的基本假设入手得出液固色谱过程中流动相组成与K′关系的一般方程,且将其系统化。结果表明,本文的一般方程能够全面地反映各因素对流动相组成与K′关系的影响。
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| 关 键 词： | 液固色谱 保留值方程 流动相组成 |
A Systematic Investigation on the Retention Value Equation in Liquid-solid Chromatography |
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| Wu Yieping Zhang Weibing. A Systematic Investigation on the Retention Value Equation in Liquid-solid Chromatography[J]. Journal of Science of Teachers＇College and University, 1994, 0(1) |
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| Authors: | Wu Yieping Zhang Weibing |
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| Affiliation: | Wu Yieping Zhang Weibing(Qiqihar Light Industry Institute)Peng Liping(Heilongjiang Instrumental Analysis Centre) |
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| Abstract: | In this paper the retention value relationships to some former model theory are investigated. In accordance with statistical thermodynaics and the elementary hypothesis of chromatography thermodynamics, the general relationship between retention value and mobile phase composition is derived. The results show our general relationship can not only systematize model theories, but also comprehensively reflect the effect facts. |
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| Keywords: | Liquid-solid chromatography Retention value equation Mobioe phase composition |
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