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铜器文物用气相缓蚀剂(VCI)的研究
引用本文:丁艳梅,许淳淳,王菊琳. 铜器文物用气相缓蚀剂(VCI)的研究[J]. 北京化工大学学报(自然科学版), 2006, 33(2): 68-71
作者姓名:丁艳梅  许淳淳  王菊琳
作者单位:北京化工大学材料科学与工程学院 北京 100029
摘    要:采用气相甄别法和封闭空间挥发减量法研究了多种气相缓蚀剂(VCI)对铜器文物的缓蚀效果,以此为基础,研制出了缓蚀性能优异的复合气相缓蚀剂,其缓蚀率达到94.5%。用扫描电子显微镜(SEM)研究了该缓蚀剂吸附在铜器文物上形成的自组装缓蚀膜的形貌,对其缓蚀机理进行了初步探讨。

关 键 词:铜器文物  气相缓蚀剂(VCI)  气相甄别法  缓蚀率  自组装  铜器文物  气相缓蚀剂(VCI)  气相甄别法   缓蚀率   自组装
收稿时间:2005-09-15
修稿时间:2005-09-15

Comparative study of volatile corrosion inhibitors (VCI) for bronze cultural relics
DING Yan-mei,XU Chun-chun,WANG Ju-lin. Comparative study of volatile corrosion inhibitors (VCI) for bronze cultural relics[J]. Journal of Beijing University of Chemical Technology, 2006, 33(2): 68-71
Authors:DING Yan-mei  XU Chun-chun  WANG Ju-lin
Affiliation:college of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China
Abstract:Volatile rust proofing sieve and closed space volatile weight-loss methods were adopted to study the inhibition efficiency of four volatile corrosion inhibitors(VCI).The best VCI were then selected and a composite.VCI was prepared;the inhibition efficiency of the composite was 94.5%.The results show that the composite VCI exhibits a good protective effect for bronze cultural relics;The formation of a self-assembled monolayer film between the VCI and bronze cultural relics was demonstrated by SEM.The inhibition mechanism of composite VCI was also studied.
Keywords:bronze cultural relics  volatile corrosion inhibitor(VCI)  volatile rust proofing sieve  inhibition efficiency  self-assembled
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