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聚丙烯/蒙脱土复合材料的热氧老化性能
引用本文:杨瑞成,马建忠,陈奎,胡天江.聚丙烯/蒙脱土复合材料的热氧老化性能[J].兰州理工大学学报,2007,33(3):8-11.
作者姓名:杨瑞成  马建忠  陈奎  胡天江
作者单位:兰州理工大学,甘肃省有色金属新材料省部共建国家重点实验室,甘肃,兰州,730050;兰州理工大学,有色金属合金省部共建教育部重点实验室,甘肃,兰州,730050;兰州理工大学,甘肃省有色金属新材料省部共建国家重点实验室,甘肃,兰州,730050
摘    要:用3种蒙脱土(原土、OMMT1、OMMT2)与聚丙烯分别熔融插层复合.经X射线衍射(XRD)分析表明,3种蒙脱土均与聚丙烯成功插层复合,制备出聚丙烯/蒙脱土纳米复合材料.重点研究聚丙烯/蒙脱土纳米复合材料的热氧老化性能.结果表明,在聚丙烯材料中,添加少量蒙脱土不但可以提高材料的力学性能,而且明显改善材料的抗热氧老化性能.对3种PP/MMT复合材料热氧老化样品进行傅立叶红外(FTIR)分析和表面形貌观察,发现蒙脱土片层在聚丙烯中插层复合越充分(乃至剥离),其抗热氧老化效果就越明显.

关 键 词:聚丙烯  蒙脱土  复合材料  热氧老化
文章编号:1673-5196(2007)03-0008-04
修稿时间:2006-06-30

Thermal oxidative aging performance of polypropylene/montmorillonite composites
YANG Rui-cheng,MA Jian-zhong,CHEN Kui,HU Tian-jiang.Thermal oxidative aging performance of polypropylene/montmorillonite composites[J].Journal of Lanzhou University of Technology,2007,33(3):8-11.
Authors:YANG Rui-cheng  MA Jian-zhong  CHEN Kui  HU Tian-jiang
Institution:1. State Key Lab. of Gansu Advanced Non-ferrous Metal Materials, Lanzhou Univ. of Tech. , Lanzhou 730050, China; 2. Key Lab. of Non-ferrous Metal Alloys, The Ministry of Education, Lanzhou Univ. of Tech. , Lanzhou 730050, China
Abstract:Three kinds of montmorillonites(pristine montmorillonites,organic modified montmorillonite 1,organic modified montmorillonite 2) were used to prepare polypropylene/montmorillonite(PP/MMT) nanocomposites by using direct melt intercalation technique.Their X-ray diffraction(XRD) characterizations showed that these montmorillonites could be intercalated with the polypropylene to synthesize PP/MMT nanocomposites successfully.Thermal oxidative aging of PP/MMT nanocomposites was emphatically investigated.The results showed that incorporation of a small amount of montmorillonite not only could enhance mechanical properties but also could improve thermal oxidative aging performance of polymer-matrix dramatically.The results of Fourier transition infrared(FTIR) analysis of and morphology of surface observation on the three kinds of aged samples of PP/MMT nanocomposites showed that sufficient intercalation of the clay particles(exfoliated) was of great benefit to improve thermal oxidative aging performance of polymer-matrix.
Keywords:polypropylene  montmorillonite  composites  thermal oxidative aging
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