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镁合金熔炼的热力学
引用本文:陈健美,张新明,邓运来,肖阳,熊创贤,蒋浩. 镁合金熔炼的热力学[J]. 中南大学学报(自然科学版), 2006, 37(3): 427-432
作者姓名:陈健美  张新明  邓运来  肖阳  熊创贤  蒋浩
作者单位:1. 中南大学,材料科学与工程学院,湖南,长沙,410083;湖南涉外经济学院,机械工程系,湖南,长沙,410012
2. 中南大学,材料科学与工程学院,湖南,长沙,410083
基金项目:国防预研基金;高比容电子铝箔的研究开发与应用项目;湖南省自然科学基金
摘    要:根据与镁合金化有关的金属元素的热力学数据,绘制与镁合金制备相关的金属氧化物、氯化物和氟化物的生成自由能随温度变化的关系图。从物理化学的角度,研究采用熔剂法制备镁舍金铸锭熔剂处理的热力学原理,为合理选择熔剂配方提供理论依据。对稀土镁合金合金化存在的熔剂制备问题进行研究,指出了解决问题的方法。

关 键 词:镁合金  自由能  稀土金属  熔剂  熔炼  精炼  合金化
文章编号:1672-7207(2006)03-0427-06
收稿时间:2005-11-25
修稿时间:2005-11-25

Thermodynamics of melding and refining of magnesium alloys
CHEN Jian-mei,ZHANG Xin-ming,DENG Yun-lai,XIAO Yang,XIONG Chuang-xian,JIANG Hao. Thermodynamics of melding and refining of magnesium alloys[J]. Journal of Central South University:Science and Technology, 2006, 37(3): 427-432
Authors:CHEN Jian-mei  ZHANG Xin-ming  DENG Yun-lai  XIAO Yang  XIONG Chuang-xian  JIANG Hao
Affiliation:1. School of Materials Science and Engineering, Central South University, Changsha 410083, China; 2. Department of Mechanical Engineering, Hunan International Economics University, Changsha 410012, China
Abstract:The diagrams showing relations of formation free energy of the oxide, chloride and fluoride against temperature related to foundry of magnesium alloys were presented according to the thermo-dynamic data for magnesium alloying. On the physical and chemical background of melding and refining of magnesium alloys prepared by the flux treatment method, the thermodynamical principles were analyzed for the theoretic foundation of choosing flux rationally. The existing questions of preparing fluxes during melting, alloying and refining of the rare earth magnesium alloys were particularly analyzed, and the solution was presented.
Keywords:magnesium alloys  free energy   rare earth metal   fluxes   melting   refining   alloying
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