| 丙烯酸酯在乙醇中聚合反应的研究 |
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| 引用本文： | 张娓,张军营,崔卫民.丙烯酸酯在乙醇中聚合反应的研究[J].北京化工大学学报(自然科学版),2005,32(4):56-59. |
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| 作者姓名： | 张娓 张军营 崔卫民 |
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| 作者单位： | 北京化工大学材料科学与工程学院,北京,100029;河南利诺生化有限责任公司,河南,安阳,455000 |
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| 摘 要： | 以BPO为引发剂，以乙醇为溶剂，以丙烯酸、丙烯酸丁酯、甲基丙烯酸甲酯以及醋酸乙烯为单体合成了醇溶性聚丙烯酸酯共聚物。利用GPC对试验进行了跟踪，讨论了反应时间、温度、溶剂及引发剂用量对单体转化率和聚合物相对分子质量及其分布的影响。
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| 关 键 词： | 醇溶性 丙烯酸酯 转化率 相对分子质量及其分布 |
| 收稿时间： | 2004-10-12 |
| 修稿时间： | 2004年10月12日 |
Polymerization of acrylate and comonomer in alcohol |
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| ZHANG Wei,ZHANG Jun-ying,CUI Wei-min.Polymerization of acrylate and comonomer in alcohol[J].Journal of Beijing University of Chemical Technology,2005,32(4):56-59. |
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| Authors: | ZHANG Wei ZHANG Jun-ying CUI Wei-min |
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| Institution: | 1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China; 2. Linuo Bio-Chemical Corporation, Ltd, Henan Anyang 455000, China |
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| Abstract: | The goal of this paper is to develop an alcohol-soluble polyacrylate. In the polymerization system, BPO was employed as an initiator, ethanol as a solvent acrylic-acid, butyl acrylate, methyl methacrylate and vinyl acetate as monomers. The reaction process was followed by GPC. The influence of the reaction conditions(such as time, temperature, amount of solvent and initiator) on the monomer conversion and the molecular weight and its distribution of the polymers was discussed. |
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| Keywords: | alcohol-soluble acrylate monomer conversion molecular weight and its distribution |
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