| （苯膦酸－磷酸氢）锆－氯化铁复合物催化F－C烷基化反应研究 |
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| 引用本文： | 傅相锴,胡传义, 温淑英. （苯膦酸－磷酸氢）锆－氯化铁复合物催化F－C烷基化反应研究[J]. 西南师范大学学报(自然科学版), 1995, 0(3) |
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| 作者姓名： | 傅相锴 胡传义 温淑英 |
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| 作者单位： | 西南师范大学化学化工学院，西南师范大学成人教育学院 |
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| 摘 要： | 首次制得（苯膦酸—磷酸氢）锆－氯化铁复合物Ｚｒ（Ｏ＿３ＰＣ＿６Ｈ＿５）（ＨＰＯ＿４）（Ｈ＿２Ｏ）＿０．３５［ＦｅＣｌ＿２（ＯＨ）］＿０．６５该复合物在空气中稳定、不易吸潮、不冒烟，对于卤代烷与芳香烃在液相的Ｆ－Ｃ烷基化反应有较好的催化活性。反应的优点是：反应条件温和，收率高，操作方便，后处理简单，催化剂重复使用性好。
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| 关 键 词： | （苯膦酸－磷酸氢）锆；氯化铁；复合物；卤代烷；F－C烷基化反应 |
FRIEDEL-CRAFTS ALKYLATION CATALYZED BY ZIRCONIUM PHENYLPHOSPHONATE-PHOSPHATE-FERRIC CHLORIDE COMPLEX |
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| Fu Xiangkai,Hu Chuanyi. FRIEDEL-CRAFTS ALKYLATION CATALYZED BY ZIRCONIUM PHENYLPHOSPHONATE-PHOSPHATE-FERRIC CHLORIDE COMPLEX[J]. Journal of southwest china normal university(natural science edition), 1995, 0(3) |
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| Authors: | Fu Xiangkai Hu Chuanyi |
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| Abstract: | Zirconium phenylphosphonate-phosphate- Ferric chloride complex,Zr(O_3PC_6H_5)(HPO_4)(H_2O)_0.35[FeCl_2(OH)]_0.65, was prepared for the first time, The complex is low hygroscopic, with nofumes and is stable in air. The complex shows fairly good catalytic activity in Friedel-Crafts alkylationof aromatic hydrocarbons with alkyl halides in liquid phase. The advantages of the reaction are as fol-lows:milder reaction condition,high yields of products,easy oporation,simple working up,and thereuse of the catalyst . |
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| Keywords: | Zirconium phenylphosphonate-phosphate ferric chloride comp1exes a1kyl halide friedel-crafts alkylation |
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