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银氨蒙脱土/聚丙烯酸钠-丙烯酰胺复合材料的制备与调湿抗菌性能
引用本文:王吉会,王志伟,张子洋,王春芳.银氨蒙脱土/聚丙烯酸钠-丙烯酰胺复合材料的制备与调湿抗菌性能[J].天津大学学报(自然科学与工程技术版),2009,42(6):507-512.
作者姓名:王吉会  王志伟  张子洋  王春芳
作者单位:天津大学材料科学与工程学院天津市材料复合与功能化重点实验室,天津,300072  
基金项目:天津市应用基础及前沿技术研究计划重点项目,武汉理工大学硅酸盐材料工程教育部重点实验室开放基金 
摘    要:通过插层聚合方法,制备出银氨蒙脱土/聚丙烯酸钠-丙烯酰胺共聚物复合调湿抗菌材料,并对材料的表面形貌、结构、吸放湿和抗菌性能进行了研究.实验结果表明,共聚物复合调湿抗菌材料的结构疏松,表面存在较大孔隙;丙烯酸.丙烯酰胺分子单体经插层聚合成功地引入到蒙脱土层间,层间距扩大为2.143nm.与聚丙烯酰胺、银氨蒙脱土/聚丙烯酰胺材料相比,银氨蒙脱土/聚丙烯酸钠-丙烯酰胺共聚物复合材料具有较高的吸放湿容量和吸放湿速度;且对大肠杆菌和藤黄微球菌具有较强的抑菌效果,抑菌率均在90%以上.

关 键 词:蒙脱土  丙烯酸钠-丙烯酰胺  复合材料  结构  调湿  抗菌

Synthesis, Humidity Controlling and Antibacterial Behaviors of [Ag(NH3)2]+Modified Montmorillonite / Polysodium Acrylate-Acrylamide Composite
WANG Ji-hui,WANG Zhi-wei,ZHANG Zi-yang,WANG Chun-fang.Synthesis, Humidity Controlling and Antibacterial Behaviors of [Ag(NH3)2]+Modified Montmorillonite / Polysodium Acrylate-Acrylamide Composite[J].Journal of Tianjin University(Science and Technology),2009,42(6):507-512.
Authors:WANG Ji-hui  WANG Zhi-wei  ZHANG Zi-yang  WANG Chun-fang
Institution:(Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering,Tianjin University,Tianjin 300072,China)
Abstract:Ag(NH3)2]^+ modified montmorillonite/polysodium acrylate-acrylamide (sMMT/copolymer)composite was synthesized by water solution intercalation and polymerization methods, and then the surface morphology, structure, humidity controlling and antibacterial behaviors of sMMT/copolymer composite were analyzed. The results show that the sMMT/ copolymer composite is loose and porous on surface. The acrylate-acrylamide monomer is successfully intercalated into the layers of montmorillonite,and the distance between two layers is increased to 2.143 nm. Compared with polyacrylamide (PAM) ,montmorillonite/polyacrylamide (sMMT/PAM) composite,the as-prepared sMMT/copolymer composite has a greater capacity and higher speed of humidity absorption and desorption. By using E Coli and Micrococcus Luteus as detective bacteria, sMMT/copolymer composite has a very good antibacterial effect with the antibacterial rate above 90%.
Keywords:montmorillonite  sodium acrylate-acrylamide  composite  structure  humidity controlling  antibacterial
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