Extraction of Aminobenzoic Acid with TOA and TBP |
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作者姓名: | 张瑾 戴猷元 |
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作者单位: | ZHANG Jin ***,DAI Youyuan ** Department of Chemical Engineering,Tsinghua University,Beijing 100084,China |
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基金项目: | the National Natural Science Foundationof China (No.2 9836 130 |
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摘 要: | IntroductionThe separation technique of solvent extractionbased on reversible chemicalcomplexation can havehigh capacity and high selectivity for separatingpolar organic solutes from dilute solutions1,2 ] .Many researchers have investigated the extractio…
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Extraction of Aminobenzoic Acid with TOA and TBP |
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Abstract: | A series of extraction equilibrium experiments for aminobenzoic acid were carried out. Tri-n-octylamine (TOA) and tributyl phosphate (TBP) were selected as complexing agents. 1-Octanol and kerosene were selected as diluents. The effects of extractant concentration and pH on the distribution ratio were discussed in detail. It was found that there are ion-pair association and hydrogen-bond complexing in the extraction. Expressions of the equilibrium distribution for different solvent systems are proposed. The precision of the models is satisfactoy. |
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Keywords: | extraction based on chemical complexation aminobenzoic acid tri n octylamine tributyl phosphate |
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