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pH值对催化湿法氧化降解垃圾渗滤液的影响
引用本文:李海生,刘亮,李鱼,刘光辉,王健,王月,刘鸿亮,陈复.pH值对催化湿法氧化降解垃圾渗滤液的影响[J].吉林大学学报(理学版),2004,42(1):147-149.
作者姓名:李海生  刘亮  李鱼  刘光辉  王健  王月  刘鸿亮  陈复
作者单位:北京化工大学化学化工学院,北京,100029;吉林大学环境与资源学院,长春,130023;中国环境科学研究院,北京,100012
基金项目:国家环保总局环境工程评估中心基金(批准号:02220100000549),吉林省环境保护补助基金(批准号:吉环科字第03-07号).
摘    要:研究了不同初始pH值对催化湿法氧化降解垃圾渗滤液总有机碳(TOC)去除率的影响及其原因, 分析了催化剂溶解与反应液pH值变化的对应关系, 并利用Elovich方程描述了降解反应的动力学过程, 建立了速率常数k值与初始pH值之间的关系.

关 键 词:pH值  催化湿法氧化  垃圾渗滤液  污水处理
文章编号:1671-5489(2004)01-0147-03
收稿时间:2003-09-09
修稿时间:2003年9月9日

Effect of pH value on decomposition of leachates by CWAO
LI Hai-sheng,LIU Liang,LI Yu,LIU Guang-hui,WANG Jian,WANG Yue,LIU Hong-liang,CHEN Fu.Effect of pH value on decomposition of leachates by CWAO[J].Journal of Jilin University: Sci Ed,2004,42(1):147-149.
Authors:LI Hai-sheng  LIU Liang  LI Yu  LIU Guang-hui  WANG Jian  WANG Yue  LIU Hong-liang  CHEN Fu
Institution:1. College of Chemical Engineering, Beijing University of Chemical Technology; Beijing 100029, China; 2. College of Environment and Resources, Jilin University, Changchun 130023, China; 3. Chinese Research Academy of Environmental Science, Beijing 100012, China
Abstract:The effect of initial pH values on the degradation efficiency of the landfill leachates by catalytic wet air oxidation(CWAO) was studied and the relationship between pH value and the dissolution of the catalyst was investigated. Meanwhile, the kinetic process of the decomposition is described with Elovich equation, and the correction relationship is also described between initial pH value and the removal rate of the dissolution of the landfill leachates used.
Keywords:pH value  catalytic wet air oxidation  landfill leachates  sewerage treatment
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