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侧基含磷阻燃共聚酯/BaSO4纳米复合材料的合成与性能研究
引用本文:曲铭海,葛欣国,王德义,王玉忠. 侧基含磷阻燃共聚酯/BaSO4纳米复合材料的合成与性能研究[J]. 四川大学学报(自然科学版), 2006, 43(2): 408-413
作者姓名:曲铭海  葛欣国  王德义  王玉忠
作者单位:四川大学化学学院,降解与阻燃高分子材料研究中心,成都,610064;四川大学化学学院,降解与阻燃高分子材料研究中心,成都,610064;四川大学化学学院,降解与阻燃高分子材料研究中心,成都,610064;四川大学化学学院,降解与阻燃高分子材料研究中心,成都,610064
基金项目:国家自然科学基金;; 国家863计划基金(2003AA302550)
摘    要:采用原位聚合法(in-situpolymerization),由对苯二甲酸(TPA)、乙二醇(EG)、阻燃单体9,10-二氢-9-氧杂-10-磷酰杂菲-丁二酸(DDP)和纳米BaSO4制备了侧基含磷阻燃共聚酯/BaSO4纳米复合材料,对反应产物结构进行了表征.通过对产物燃烧和热稳定性的研究,发现产物具有良好的阻燃和耐熔滴性能.

关 键 词:含磷共聚酯  阻燃  熔滴  纳米复合材料
文章编号:0490-6756(2006)02-0408-06
收稿时间:2006-02-23
修稿时间:2006-02-23

Synthesis and Properties of Flame Retardant Copolyesters Containing Phosphorus Linked Pendent Groups/BaSO_(4) Nanocomposites
QU Ming-hai,GE Xin-guo,WANG De-yi,WANG Yu-zhong. Synthesis and Properties of Flame Retardant Copolyesters Containing Phosphorus Linked Pendent Groups/BaSO_(4) Nanocomposites[J]. Journal of Sichuan University (Natural Science Edition), 2006, 43(2): 408-413
Authors:QU Ming-hai  GE Xin-guo  WANG De-yi  WANG Yu-zhong
Affiliation:Center for Degradable and Flame-Retardant Polymeric Materials; College of Chemistry; Sichuan University,Center for Degradable and Flame-Retardant Polymeric Materials; College of Chemistry; Sichuan University,Center for Degradable and Flame-Retardant Polymeric Materials; College of Chemistry; Sichuan University,Center for Degradable and Flame-Retardant Polymeric Materials; College of Chemistry; Sichuan University
Abstract:The flame retardant copolyesters containing phosphorus linked pendent groups/BaSO_(4) nanocomposite,derived from 9,10-dihydro-10 [2,3-di(hydroxycarbonyl) propyl] 10-phosphaphenanthrene-10-oxide(DDP), terephthalic acid(TPA),ethylene glycol(EG) and the barium sulfate sol were synthesized by in-situ polycondensation.The resulting materials were characterized by FTIR,()~(1)HNMR and TEM.The thermal stability,flammability and flame retardancy were also investigated.The results showed that this kind of nanocomposi
Keywords:phosphorus-containing copolyester   flame retardant   melt-dripping   nanocomposite  
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