Eine neue Umlagerungsreaktion und ein neues Prinzip zum Aufbau von Peptidketten |
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| Authors: | M Brenner J P Zimmermann J Wehrmüller P Quitt Iphigenia Photaki |
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| Institution: | (1) Organisch-Chemische Anstalt der Universität Basel, Switzerland |
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| Abstract: | Summary In a series of model reactions, it is shown that residues of -aminoacids may be inserted by a particular rearrangement into certain carboxyl or carbonylamido groups. Repeated insertion results in the formation of a peptide derivative. It is concluded that natural peptides or proteins must not necessarily be formed by head to tail combination of aminoacids. Other implications of the new principle are discussed.
Vorgetragen am XIV. Internationalen Kongress für Reine und Angewandte Chemie, 21. bis 27. Juli 1955, Zürich. |
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