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电弧喷涂Zn-Al-Mg-La-Ce涂层的耐腐蚀性能
引用本文:邢士波,肖葵,李丽,李晓刚,刘安强,王恩清. 电弧喷涂Zn-Al-Mg-La-Ce涂层的耐腐蚀性能[J]. 北京科技大学学报, 2012, 34(10): 1167-1172
作者姓名:邢士波  肖葵  李丽  李晓刚  刘安强  王恩清
作者单位:1. 北京科技大学新材料技术研究院,北京100083 河北工程大学机电学院,邯郸056038
2. 北京科技大学新材料技术研究院,北京,100083
3. 河北工程大学机电学院,邯郸,056038
4. 新兴铸管集团有限公司技术中心,邯郸,056300
基金项目:国家科技基础条件平台资助项目(2005DKA10400);国家自然科学基金资助项目(50871021)
摘    要:采用电弧喷涂法制备Zn-Al-Mg-La-Ce涂层,通过盐雾试验对涂层进行腐蚀,利用能谱分析、X射线衍射分析、扫描电镜观察、极化曲线以及电化学阻抗谱等手段对腐蚀前后的Zn-Al-Mg-La-Ce涂层进行了研究.结果表明:实验制备的Zn-Al-Mg-La-Ce涂层具有较好的自封闭效果,组织致密,在腐蚀过程中表面的微观孔隙能够被自身的腐蚀产物有效堵塞,涂层表面形成的致密腐蚀产物层能够阻止腐蚀的进一步发生.因此,Zn-Al-Mg-La-Ce涂层具有优异的耐蚀性能.

关 键 词:锌铝合金  稀土  涂层  耐腐蚀性  喷涂

Corrosion resistance of Zn-Al-Mg-La-Ce coatings by electric arc spraying
XING Shi-bo,XIAO Kui,LI Li,LI Xiao-gang,LIU An-qiang,WANG En-qing. Corrosion resistance of Zn-Al-Mg-La-Ce coatings by electric arc spraying[J]. Journal of University of Science and Technology Beijing, 2012, 34(10): 1167-1172
Authors:XING Shi-bo  XIAO Kui  LI Li  LI Xiao-gang  LIU An-qiang  WANG En-qing
Affiliation:1) Institute of Advanced Materials and Technology,University of Science and Technology Beijing,Beijing 100083,China 2) College of Mechanical and Electrical Engineering,Hebei University of Engineering;Handan 056038,China 3) Technology Center,Xinxing Ductile Iron Pipe Group Company,Handan 056300,China
Abstract:Zn-Al-Mg-La-Ce coatings were prepared by electric arc spraying,and their corrosion behavior was studied with salt spray test.The characteristics of the coatings before and after corrosion were investigated by energy dispersive spectrometry(EDS),X-ray diffraction(XRD),scanning electron microscopy(SEM),polarization curves,and electrochemical impedance spectroscopy.It is shown that the coatings have outstanding self-sealing effectiveness,and their structures are compact.During corrosion,microscopic pores on the surfaces of the coatings can be jammed with their own corrosion products,thus forming a dense corrosion product layer to prevent from further corrosion.Consequently,the corrosion resistance of Zn-Al-Mg-La-Ce coatings is superior to that of normal coatings.
Keywords:zinc aluminum alloys  rare earths  coatings  corrosion resistance  spraying
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