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聚丁二烯/黏土纳米复合凝胶的流变行为研究
引用本文:朱建君,郭鹏,黄克靖,雷忠良.聚丁二烯/黏土纳米复合凝胶的流变行为研究[J].信阳师范学院学报(自然科学版),2011,24(1):115-119.
作者姓名:朱建君  郭鹏  黄克靖  雷忠良
作者单位:信阳师范学院,化学化工学院,河南,信阳,464000
摘    要:在恒定剪切速率下,利用旋转流变仪研究遥爪型聚丁二烯液体橡胶/有机黏土纳米复合凝胶的流变行为,同时利用X-射线衍射(XRD)和透射电镜(TEM)等表征手段研究其微观结构.通过对此类纳米复合凝胶流变行为的测试,实现黏土片层在遥爪型聚丁二烯液体橡胶中分散过程的原位观测,并总结出影响遥爪型聚丁二烯液体橡胶/有机黏土纳米复合凝胶流变行为的主要因素.

关 键 词:端羟基聚丁二烯  端羧基聚丁二烯  有机黏土  流变性

Studies on the Rheological Behavior of Polybutadiene/Clay Nanocomposite Gels
ZHU Jian-jun,GUO Peng,HUANG Ke-jing,LEI Zong-Liang.Studies on the Rheological Behavior of Polybutadiene/Clay Nanocomposite Gels[J].Journal of Xinyang Teachers College(Natural Science Edition),2011,24(1):115-119.
Authors:ZHU Jian-jun  GUO Peng  HUANG Ke-jing  LEI Zong-Liang
Institution:ZHU Jian-jun,GUO Peng,HUANG Ke-jing,LEI Zong-liang(College of Chemistry and Chemical Engineering,Xinyang Normal University,Xinyang 464000,China)
Abstract:The rheological behavior of telechelic liquid polybutadiene rubber/organoclay nanocomposite gels has been studied under the steady shear performed on a HAAKE RheoStress 600 instrument.And the microstructure of nanocomposite gels was characterized by X-ray diffraction(XRD) and transmission electron microscopy(TEM).The in-situ dispersion process of organoclay in telechelic liquid polybutadiene rubber was observed by rheological experiments,and some controlling factors were proposed to explain the rheological ...
Keywords:hydroxyl-terminated polybutadiene  carboxyl-terminated polybutadiene  organoclay  rheological behavior  
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