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Spontaneous formation of tubular microstructure vesicle from PTA/SDS system
作者姓名:WANGZhengwu  CHENWenjun  LIUXiaojun  LIGanzuo  ZHENGLiqiang  ZHANGJin  HUANGDongyang
作者单位:[1]KeyLaboratoryofColloidandInterfaceChemistryofMinistryofEducation,ShandongUniversity,Jinan250100,China [2]SchoolofChemicalandMaterialEngineering,SouthernYangtzeUniversity//KeyLaboratoryofColloidandInterfaceChemistryofMinistryofEducation,ShandongUniversity//MedicalCollege,ShantouUniversity [3]KeyLaboratoryofCrystalMaterialofChina,ShandongUniversity,Jinan250100.China [4]MedicalCollege,ShantouUniversity,Shantou515031,China
摘    要:Spontaneous vesicle formation and transformation of vesicle to tubular microstructure have been observed in aqueous mixtures of tri-(n-dodecyl-dimethyl-hydroxy-propylammonium chloride) phosphate (PTA) and sodium dedecyl sulfate (SDS), which is supported by negative-staining transmission electron microscopy (TEM), scan electron microscopy (SEM) and dynamic light scattering (DLS). Spherical vesicles aggregate to tubular microstructures with their diameters and lengths respectively of about 100 and 7000 nm in the freshly prepared sample at the molar ratio of PTA/SDS=3/7 and a total surfactant concentration of 0.01 mol/L. The diameter, the length and the quantity of tubular structures all increase with the increase of the total concentration of surfactant and the sample aging.

关 键 词:囊泡  管状显微结构  磷酸盐  负着色TEM
收稿时间:6 April 2004

Spontaneous formation of tubular microstructure vesicle from PTA/SDS system
WANGZhengwu CHENWenjun LIUXiaojun LIGanzuo ZHENGLiqiang ZHANGJin HUANGDongyang.Spontaneous formation of tubular microstructure vesicle from PTA/SDS system[J].Chinese Science Bulletin,2005,50(9):857-861.
Authors:Wang Zhengwu  Chen Wenjun  Liu Xiaojun  Li Ganzuo  Zheng Liqiang  Zhang Jin  Huang Dongyang
Institution:(1) School of Chemical and Material Engineering, Southern Yangtze University, 214036 Wuxi, China;(2) Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, 250100 Jinan, China;(3) Medical College, Shantou University, 515031 Shantou, China;(4) Key Laboratory of Crystal Material of China, Shandong University, 250100 Jinan, China
Abstract:Spontaneous vesicle formation and transforma- tion of vesicle to tubular microstructure have been observed in aqueous mixtures of tri-(n-dodecyl-dimethyl-hydroxy- propylammonium chloride) phosphate (PTA) and sodium dedecyl sulfate (SDS), which is supported by negative-stain- ing transmission electron microscopy (TEM), scan electron microscopy (SEM) and dynamic light scattering (DLS). Spherical vesicles aggregate to tubular microstructures with their diameters and lengths respectively of about 100 and 7000 nm in the freshly prepared sample at the molar ratio of PTA/SDS=3/7 and a total surfactant concentration of 0.01 mol/L. The diameter, the length and the quantity of tubular structures all increase with the increase of the total concen- tration of surfactant and the sample aging.
Keywords:tri-(n-dodecyl-dimethyl-hydroxypropylammonium chlor-  ide) phosphate (PTA)  vesicle  tubular microstructure  negative-  staining TEM    
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