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| 乙酸联吡啶合钴配合物的合成及晶体结构 | |
| 引用本文： | 张淑华,蒋毅民,张桂英,马录芳. 乙酸联吡啶合钴配合物的合成及晶体结构[J]. 广西师范大学学报(自然科学版), 2004, 22(4): 53-56 |
| 作者姓名： | 张淑华 蒋毅民 张桂英 马录芳 |
| 作者单位： | 1. 桂林工学院,材料与化学工程系,广西,桂林,541004 2. 广西师范大学,化学化工学院,广西,桂林,541004 3. 洛阳师范学院,化学系,河南,洛阳,471022 |
| 基金项目： | Science Foundation of Guangxi (0 3 3 90 3 4)，Foundation of Ministry Education of Guangxi ([2 0 0 4]2 0 ) |
| 摘 要： | 合成了标题化合物[Co(bpy)2(CH3COO)]·(CH3COO)·5(H2O),并制得了单晶,采用单色MoKα(λ=0.071 073 nm)射线测定,结果表明该化合物属单斜晶系,空间群C2/c,其晶胞参数为a=1.0945(2) nm, b=1.605 6(3) nm,c=1.445 5(2) nm.β=101.974(3)°,V=2.485 0(7) nm3,Z=4,Dc=1.549g/cm3,μ= 0.753 mm-1,F(000)=1 212.2个2,2′-联吡啶提供4个氮原子参与配位,醋酸根提供2个氧原子参与配位,该配合物是六配位的变形八面体构型. |
| 关 键 词： | 钴（Ⅱ）配合物 2，2′-联吡啶 晶体结构 |
SYNTHESIS AND CRYSTAL STRUCTURE OF [Co(bpy)2(Ac)]·Ac·5H2O |
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| Abstract. SYNTHESIS AND CRYSTAL STRUCTURE OF [Co(bpy)2(Ac)]·Ac·5H2O[J]. Journal of Guangxi Normal University(Natural Science Edition), 2004, 22(4): 53-56 | |
| Authors: | Abstract |
| Abstract: | The title complex was synthesized by reaction of 2,2′-bipyridine (bpy) and cobalt acetate in water-ethanol solution.The crystal structure was determined by X-ray diffraction method.The crystal structure belongs to monoclinic system with space group C2/cand cell parameters:a=1.094 5(2) nm,b=1.605 6(3) nm,c=1.445 5(2) nm.β=101.974(3)°,V=2.485 0(7) nm3,Z=4,Dc=1.549 g/cm3,μ= 0.753mm-1 and F(000)=1 212.The Co(Ⅱ) is coordinated by four N atoms from two bpy and two O atoms from one acetate group to form a slightly distorted octahedron geometry. |
| Keywords: | cobalt complex 2,2′-bipyridine crystal structure |
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