Microstructure and properties of mullite-based porous ceramics produced from coal fly ash with added Al2O3 |
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作者姓名: | Jian-bin Zhu Hong Yan |
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作者单位: | Department of Materials Processing Engineering, School of Mechanical Electrical Engineering, Nanchang University, Nanchang 330000, China |
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基金项目: | This study was financially supported by the Project of theScience and Technology Creative Team of Universities inJiangxi Province, China;by the OpenFoundation of Jiangxi Key Laboratory for Advanced Copperand Tungsten Materials |
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摘 要: | Using coal fly ash slurry samples supplemented with different amounts of Al2O3, we fabricated mullite-based porous ceramics via a dipping-polymer-replica approach, which is a popular method suitable for industrial application. The microstructure, phase composition, and compressive strength of the sintered samples were investigated. Mullite was identified in all of the prepared materials by X-ray diffraction analysis. The microstructure and compressive strength were strongly influenced by the content of Al2O3. As the Al/Si mole ratio in the starting materials was increased from 0.84 to 2.40, the amount of amorphous phases in the sintered microstructure decreased and the compressive strength of the sintered samples increased. A further increase in the Al2O3 content resulted in a decrease in the compressive strength of the sintered samples. The mullite-based porous ceramic with an Al/Si molar ratio of 2.40 exhibited the highest compressive strength and the greatest shrinkage among the investigated samples prepared using coal fly ash as the main starting material.
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关 键 词: | porous materials ceramics fly ash mullite aluminum oxide |
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