| 有机二硫化物CE反应机理的电极过程动力学 |
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| 引用本文： | 苏育志,翁国明,刘兆清.有机二硫化物CE反应机理的电极过程动力学[J].广州大学学报(自然科学版),2009,8(3). |
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| 作者姓名： | 苏育志 翁国明 刘兆清 |
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| 作者单位： | 广州大学化学化工学院,广东,广州,510006 |
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| 基金项目： | 国家自然科学基金资助项目 |
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| 摘 要： | 对新型有机二硫化物单体的电化学行为进行了讨论并分析其CE反应机理,在电化学反应为决速步时的条件下,利用电化学反应动力学方程推导其动力学方程,分析其动力学参数.由此可通过由旋转圆盘电极技术及静态实验方法测定出的动力学参数来确定其相应的电化学反应机理及电极动力学方程.
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| 关 键 词： | 有机二硫化物 电化学动力学 储能材料 |
Electrode kinetics of organodisulfides in CE route |
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| SU Yu-zhi,WENG Guo-ming,LIU Zhao-qing.Electrode kinetics of organodisulfides in CE route[J].Journal og Guangzhou University:Natural Science Edition,2009,8(3). |
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| Authors: | SU Yu-zhi WENG Guo-ming LIU Zhao-qing |
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| Institution: | School of Chemistry and Chemical Engineering;Guangzhou University;Guangzhou 510006;China |
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| Abstract: | In this paper,the electrochemical behavior and the CE reaction mechanisms of the novel organodisulfides are studied. It is to deduce their kinetic equations and analyze their kinetic parameters by using the classical electrochemical equation on condition that electrochemical reaction is the rate determining step. Therefore the corresponding electrochemical reaction mechanisms and electrode kinetic equations can be determined as a basis for the kinetic parameters which were measured by rotating disk electrod... |
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| Keywords: | organodisulfide electrochemistry kinetics energy storage material |
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