| 基于CH_4/m-C_9H_(12)二元体系汽液相平衡实验的CH_4/C_2H_4/m-C_9H_(12)三元体系的模拟研究 |
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| 引用本文： | 邓玮,郑丹星,武向红,郭亮. 基于CH_4/m-C_9H_(12)二元体系汽液相平衡实验的CH_4/C_2H_4/m-C_9H_(12)三元体系的模拟研究[J]. 北京化工大学学报(自然科学版), 2010, 37(1): 5-8. DOI: 10.3969/j.issn.1671-4628.2010.01.002 |
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| 作者姓名： | 邓玮 郑丹星 武向红 郭亮 |
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| 作者单位： | 北京化工大学化学工程学院,北京,100029;北京化工大学化学工程学院,北京,100029;北京化工大学化学工程学院,北京,100029;北京化工大学化学工程学院,北京,100029 |
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| 基金项目： | 国家自然科学基金(50890184) |
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| 摘 要： | 测定了压力0.5~3.0 MPa、温度233.15~293.15 K条件下CH4/m-C9H12(即均三甲苯)体系的二元汽液相平衡数据,用PR方程对CH4/m-C9H12体系的汽液相平衡数据进行关联,得到了二元交互作用参数。实验数据的偏差分析证明PR方程适合描述该体系。基于以上结果,并结合文献数据,计算了CH4/C2H4/m-C9H12三元体系的相平衡数据,并绘制了该三元体系的相图。结果表明,CH4和m-C9H12的相容性与C2H4和m-C9H12相比差异较大,m-C9H12是一种适合吸收C2H4的溶剂。
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| 关 键 词： | 汽液相平衡 甲烷 乙烯 均三甲苯 PR方程 |
Modeling of the phase diagram of the CH_4/C_2H_4/m-C_9H_(12)ternary system based on vapor-liquid measurements for the CH4/m-C_9H_(12) binary system |
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| DENG Wei,ZHENG DanXing,WU XiangHong,GUO Liang. Modeling of the phase diagram of the CH_4/C_2H_4/m-C_9H_(12)ternary system based on vapor-liquid measurements for the CH4/m-C_9H_(12) binary system[J]. Journal of Beijing University of Chemical Technology, 2010, 37(1): 5-8. DOI: 10.3969/j.issn.1671-4628.2010.01.002 |
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| Authors: | DENG Wei ZHENG DanXing WU XiangHong GUO Liang |
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| Affiliation: | College of Chemical Engineering;Beijing University of Chemical Technology;Beijing 100029;China |
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| Abstract: | Isothermal vapor-liquid equilibrium(VLE) data for the CH4/m-C9H12(i.e.mesitylene) binary system have been measured under pressures of 0.5 to 3.0MPa,and temperatures of 233.15 to 293.15K.The VLE data were correlated by means of the Peng-Robinson equation and the interaction coefficient was calculated.Combination of the results with other data in the literature allowed the phase equilibrium data of the CH4/C2H4/m-C9H12 ternary system to be calculated.The phase diagram was also derived.The ternary system phase... |
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| Keywords: | vapor-liquid phase equilibrium methane ethylene mesitylene Peng-Robinson equation |
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