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退火处理对镨离子掺杂钨酸铅晶体的光谱影响
引用本文:熊飞兵,黄艺东,罗遵度.退火处理对镨离子掺杂钨酸铅晶体的光谱影响[J].厦门理工学院学报,2010,18(4):11-15.
作者姓名:熊飞兵  黄艺东  罗遵度
作者单位:[1]厦门理工学院数理系,福建厦门361024 [2]中科院福建物质结构研究所,福建福州350002
基金项目:福建省自然科学基金,福建省教育厅科技项目,厦门理工学院科研启动基金
摘    要:研究退火处理对镨离子掺杂钨酸铅晶体光谱性质的影响.在常温条件下测量镨离子掺杂钨酸铅晶体退火前和退火后的偏振吸收谱、偏振荧光谱和主要荧光发射上能级的衰减曲线.研究表明退火处理可以减少大部分与氧缺乏有关的缺陷中心和与热应力有关的晶体缺陷中心;探讨了减少其它晶体缺陷中心的方法.结果表明,晶体的退火处理是一种提高镨离子掺杂钨酸铅晶体发光性能的有效方法.

关 键 词:退火处理  镨离子掺杂钨酸铅晶体  晶体缺陷  发光性质

Effect of Annealing Treatment on Spectroscopic Properties of Praseodymiumions Doped in Lead Tungstate Crystal
XIONG Fei-bing,HUANG Yi-dong,LUO Zun-du.Effect of Annealing Treatment on Spectroscopic Properties of Praseodymiumions Doped in Lead Tungstate Crystal[J].Journal of Xiamen University of Technology,2010,18(4):11-15.
Authors:XIONG Fei-bing  HUANG Yi-dong  LUO Zun-du
Institution:1.Faculty of Physics & Mathematics,Xiamen University of Technology,Xiamen 361024,China; 2.Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China)
Abstract:The effect of annealing treatment on the spectroscopic properties of Pr3+-doped PbWO4 crystals were discussed in detail.The polarized absorption spectra,polarized fluorescence spectra,and fluorescence decay curves of main emission manifolds of as-grown and annealed Pr3+-doped PbWO4 crystals were measured at room temperature and analyzed,and further methods to quench other defect centers were discussed.The results demonstrate that annealing treatment can diminish most defect centers related to oxygen vacancies and thermal stress and that annealing treatment can exert a distinct influence on the spectroscopic properties of Pr3+:PbWO4 crystal as a promising laser and phosphors material.
Keywords:annealing treatment  Pr3+-doped PbWO4  defect centers  spectroscopic properties
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