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Progress in the study of molecular organized assemblies by dielectric relaxation spectroscopy
作者姓名:ZHAO Kongshuang  HE Kejuan  WEI Suxiang
作者单位:1. Department of Chemistry, Beijing Normal University, Beijing 100875, China; 2. Department of Chemistry, South China Normal University, Guangzhou 510631, China
基金项目:教育部科学技术研究项目
摘    要:Because dielectric spectroscopy covers a great many problems in physical and chemical systems occurring in an extremely wide frequency range, the study of this method plays an important role in physical chemistry. As an effective tool to detect inner properties of substance systems, the dielectric spectroscopy method is widely used in chemical systems and has been dramatically developed in recent decade. This review paper describes the applications of the dielectric spectroscopy in the chemical field, and main concentrations are focused on the micelle, microemulsion and other so-called molecular organized assemblies. Some dielectric principles and models proposed for these systems are introduced. In addition, recent technical developments in dielectric spectroscopy and developing trend of this method in other chemical systems are reviewed.

关 键 词:dielectric  relaxation    micelle    microemulsion    vesicle    relaxation  time

Progress in the study of molecular organized assemblies by dielectric relaxation spectroscopy
ZHAO Kongshuang,HE Kejuan,WEI Suxiang.Progress in the study of molecular organized assemblies by dielectric relaxation spectroscopy[J].Progress in Natural Science,2006,16(3):221-230.
Authors:ZHAO Kongsnuang  HE Kejuan  WEI Suxiang
Institution:1. Department of Chemistry,Beijing Normal University,Beijing 100875,China;Department of Chemistry,South China Normal U-niversity,Guangzhou 510631,China
2. Department of Chemistry,Beijing Normal University,Beijing 100875,China
3. Department of Chemistry,South China Normal U-niversity,Guangzhou 510631,China
Abstract:Because dielectric spectroscopy covers a great many problems in physical and chemical systems occurring in an extremely wide frequency range, the study of this method plays an important role in physical chemistry. As an effective tool to detect inner properties of substance systems, the dielectric spectroscopy method is widely used in chemical systems and has been dramatically developed in recent decade. This review paper describes the applications of the dielectric spectroscopy in the chemical field, and main concentrations are focused on the micelle, microemulsion and other so-called molecular organized assemblies. Some dielectric principles and models proposed for these systems are introduced. In addition, recent technical developments in dielectric spectroscopy and developing trend of this method in other chemical systems are reviewed.
Keywords:dielectric relaxation  micelle  microemulsion  vesicle  relaxation time
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