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二苯胺磺酸钠对B-Z振荡反应的影响
引用本文:李奇志,刘秀辉,任杰,杨华,杨武,高锦章,邓华陵. 二苯胺磺酸钠对B-Z振荡反应的影响[J]. 西北师范大学学报(自然科学版), 2002, 38(1): 51-54
作者姓名:李奇志  刘秀辉  任杰  杨华  杨武  高锦章  邓华陵
作者单位:西北师范大学化学化工学院,西北师范大学化学化工学院,西北师范大学化学化工学院,西北师范大学化学化工学院,西北师范大学化学化工学院,西北师范大学化学化工学院,西北师范大学化学化工学院 甘肃兰州730070,甘肃兰州730070,甘肃兰州730070,甘肃兰州730070,甘肃兰州7300
基金项目:教育部高校骨干教师基金资助项目 (30 76 ),西北师范大学科技创新工程资助项目 (KJCXGC 0 1)
摘    要:研究了B-Z振荡体系在各种组不同浓度下周期和振的改变值与加入二苯胺磺酸钠浓度的关系。结果表明第一个周期改变值与加入浓度有良好线性关系,相关系数均大于0.9916。改变组分浓度,可适当提高检测浓度范围同时对反应机理进行了较为深入的探讨。

关 键 词:二苯胺磺酸钠 B-Z振荡反应 组分浓度 周期 振幅 反应机理
文章编号:1001-988X(2002)01-0051-04
修稿时间:2001-07-02

Effects of sodium diphenylamine sulfonate on the B-Z oscillating reaction
LI Qi-zhi,LIU Xiu-hui,REN Jie,YANG Hua,YANG Wu,GAO Jin-zhang,DENG Hua-ling. Effects of sodium diphenylamine sulfonate on the B-Z oscillating reaction[J]. Journal of Northwest Normal University Natural Science (Bimonthly), 2002, 38(1): 51-54
Authors:LI Qi-zhi  LIU Xiu-hui  REN Jie  YANG Hua  YANG Wu  GAO Jin-zhang  DENG Hua-ling
Abstract:The effects of sodium diphenylamine sulfonate on the B-Z oscillating chemical reaction were studied.Under the conditions of different reactants' concentration,the dependence of the period increase and the amplitude decrease on the injected concentration were reported.Results show that the change of the first oscillation period is directly proportional to the concentration of sodium diphenylamine sulfonate,and all of the related coefficients are greater than 0.9916.Experiments indicated that the variations in concentration of the reactants had an effect on the sensitivity and the accuracy for the determination,especially in the concentration of sulphuric acid.The possible reaction mechanism has been studied.
Keywords:sodium diphenylamine sulfonate  B-Z oscillating chemical reaction  concentration
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