| 取代四苯基卟啉的合成及性能研究 |
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| 引用本文： | 安悦,王烽凡,于沫函,刘文韬,邹禹. 取代四苯基卟啉的合成及性能研究[J]. 辽宁师范大学学报(自然科学版), 2014, 0(2): 227-232 |
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| 作者姓名： | 安悦 王烽凡 于沫函 刘文韬 邹禹 |
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| 作者单位： | 辽宁师范大学化学化工学院; |
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| 基金项目： | 辽宁省教育厅科学技术研究项目(2008349) |
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| 摘 要： | 以吡咯、苯甲醛为主要原料,合成得到四苯基卟啉;将其经硝化、还原、磺化反应处理,又分别得到5-(4-硝基苯基)-10,15,20-三苯基卟啉、5-(4-氨基苯基)-10,15,20-三苯基卟啉、5-(4-氨基苯基)-10,15,20-三(4-磺酸钠苯基)卟啉3种不同取代四苯基卟啉化合物,借助元素分析、红外光谱和核磁共振氢谱等手段对所合成的4种化合物进行了表征.采用紫外-可见光谱法、荧光光谱法以及循环伏安法对4种化合物的光谱性质和电化学性质进行了探究,并讨论了不同取代基的影响.
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| 关 键 词： | 四苯基卟啉 合成 紫外-可见光谱 荧光光谱 电化学 |
Synthesis and performance study of tetraphenylporphyrin and its derivatives |
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| AN Yue,WANG Feng fan,YU Mohan,LIU Wentao,ZOU Yu. Synthesis and performance study of tetraphenylporphyrin and its derivatives[J]. Journal of Liaoning Normal University(Natural Science Edition), 2014, 0(2): 227-232 |
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| Authors: | AN Yue WANG Feng fan YU Mohan LIU Wentao ZOU Yu |
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| Affiliation: | (Schoolof Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China) |
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| Abstract: | Teraphenylporphyrin and three kinds of its derivatives were synthesized by the reaction of nitration ,reduction ,sulfonation using pyrrole and benzaldehyde as the starting materials ,the struc-ture of four kinds of target compounds were identified by elemental analysis ,IR and 1 HNMR .The spectral and electrochemical behaviors of tetraphenylporphyrin and its derivatives were studied by the method of UV-Vis spectrum ,fluorescence spectrum ,cyclic voltammetry and the effects of various substituent groups on spectroscopy and electrochemistry properties were also discussed in this paper . |
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| Keywords: | tetraphenylporphyrin synthesis UV-Vis spectrum fluorescence spectrum electrochemical |
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