| (C24H16N2)3(HSiW12O40)·3DMF·4H2O的合成与表征 |
| |
| 引用本文： | 柳士忠.(C24H16N2)3(HSiW12O40)·3DMF·4H2O的合成与表征[J].湖北大学学报(自然科学版),1999(2). |
| |
| 作者姓名： | 柳士忠 |
| |
| 作者单位： | 湖北大学化学与材料科学学院!湖北武汉４３００６２ |
| |
| 基金项目： | 国家自然科学基金!2967011，湖北省教委科研基金 |
| |
| 摘 要： | 合成了一种新的电荷转移配合物（Ｃ２４Ｈ１６Ｎ２）３（ＨＳｉＷ１２Ｏ４０）·３ＤＭＦ·４Ｈ２Ｏ，用元素分析、红外、固体电子光谱、ＩＣＰ、热重分析和ＥＳＲ等手段对其进行了表征，确定了该配合物的化学组成与结构．研究表明有机电子给体与１２－钨硅杂多阴离子之间发生了电荷转移反应．
|
| 关 键 词： | 12－钨硅酸 4，7－二苯基－1，10－邻二氮菲 电荷转移配合物 合成 性质 |
Synthesis and Characterization of Organo- polyoxometalate a Charge - transferComplex (C_(24)H_(16)N_2 )3 (HSiW_(12)O_(40) ) 3DMF 4H_2O |
| |
| Liu Shizhong, Zhang Weihua.Synthesis and Characterization of Organo- polyoxometalate a Charge - transferComplex (C_(24)H_(16)N_2 )3 (HSiW_(12)O_(40) ) 3DMF 4H_2O[J].Journal of Hubei University(Natural Science Edition),1999(2). |
| |
| Authors: | Liu Shizhong Zhang Weihua |
| |
| Abstract: | A new 0rgano - Polyoxometalate Charge - tranSfer Complex(C24 H16 N2 )3 (HSiWI12 O40 ) 3DMF4H2 O were synthesized and chazacterized by elemental analysis, FTIR, J], solid electal spectra, ICP, re and ESRtechnology. The results indicate that there is charge transfer between the 4, 7 - Diphenyl - l, 10- phenanthndin andthe polyboon take place in the compound. |
| |
| Keywords: | a - H4SiW12 O40 4 7 - Diphenyl -l 10 - Phenanthiolin Charge - transfer complex Synthesis Characterization |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
