| 二卤代烷烃与甲酸甲酯的光促进羰基化反应 |
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| 引用本文： | 胡耀云,贾颖萍,崔颖娜,尹静梅. 二卤代烷烃与甲酸甲酯的光促进羰基化反应[J]. 鞍山科技大学学报, 2011, 0(2) |
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| 作者姓名： | 胡耀云 贾颖萍 崔颖娜 尹静梅 |
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| 作者单位： | 辽宁科技大学化学工程学院;大连大学生物有机省重点实验室; |
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| 摘 要： | 在光促进温和条件下,以甲酸甲酯为C1源,研究了非贵金属钴盐、铜盐催化二卤代烷烃(1,6-二溴己烷和1-氯-6-溴己烷)的羰基化反应。实验表明,1,6-二溴己烷和1-氯-6-溴己烷都是发生单羰基化反应,而且是C-Br键发生反应,分别得到的卤代羧酸甲酯为Br(CH2)6CO2CH3和Cl(CH2)6CO2CH3。
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| 关 键 词： | 光促进羰基化反应 二卤代烷烃 甲酸甲酯 钴盐 铜盐 |
Photopromoted carbonylation of dihaloalkanes with methyl formate |
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| HU Yao-yun,JIA Ying-ping,CUI Ying-na,YIN Jing-mei. Photopromoted carbonylation of dihaloalkanes with methyl formate[J]. Journal of Anshan University of Science and Technology, 2011, 0(2) |
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| Authors: | HU Yao-yun JIA Ying-ping CUI Ying-na YIN Jing-mei |
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| Affiliation: | HU Yao-yun1,2,JIA Ying-ping2,CUI Ying-na2,YIN Jing-mei2(1.School of Chemical Engineering,University of Science and Technology Liaoning,Anshan 114051,China,2.Liaoning Key Laboratory of Bio-organic Chemistry,Dalian University,Dalian 116622,China) |
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| Abstract: | The photopromoted carbonylation of dihaloalkanes with methyl formate catalyzed by cobalt and copper salts catalysts is studied under ambient conditions.The results indicate that the single carbonylations of 1,6-dibromohexane and 1-bromo-6-chlorohexane occurred.The corresponding monocarbonylated products Br(CH2)6CO2CH3 and Cl(CH2)6CO2CH3 are obtained. |
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| Keywords: | photopromoted carbonylation dihaloalkanes methyl formate cobalt salts copper salts |
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