| 反相微乳液中血红蛋白生物催化聚合芳杂环高分子 |
| |
| 引用本文： | 毛陆原,杨勇,申小清,王彬,赵彬,杨红霞. 反相微乳液中血红蛋白生物催化聚合芳杂环高分子[J]. 郑州大学学报(理学版), 2004, 36(3): 64-66,72 |
| |
| 作者姓名： | 毛陆原 杨勇 申小清 王彬 赵彬 杨红霞 |
| |
| 作者单位： | 郑州大学材料工程学院,郑州,450052 |
| |
| 基金项目： | 河南省自然科学基金，河南省教育厅自然科学基金 |
| |
| 摘 要： | 血红蛋白在双[2-乙基己酯]-磺酸基琥珀酸钠(Aerosol OT,AOT)形成的反相微乳液胶束中,在过氧化氢的存在下生物催化聚合邻苯二胺,所得产物与化学法合成的聚合物的热稳定性相当.推测所得产物为含有2,3-二氨基吩嗪和喹喔啉重复单元的芳杂环高分子纳米结构材料.
|
| 关 键 词： | 血红蛋白 反相微乳液 芳杂环高分子 纳米技术 生物催化聚合 |
| 文章编号： | 1671-6841(2004)03-0064-04 |
Synthesis of Aromatic Heterocyclic Polymer by Hemoglobin Encapsulated in Reversed Microemulsions |
| |
| Mao Luyuan,Yang Yong,Shen Xiaoqing,Wang Bin,Zhao Bin,Yang Hongxia. Synthesis of Aromatic Heterocyclic Polymer by Hemoglobin Encapsulated in Reversed Microemulsions[J]. Journal of Zhengzhou University(Natrual Science Edition), 2004, 36(3): 64-66,72 |
| |
| Authors: | Mao Luyuan Yang Yong Shen Xiaoqing Wang Bin Zhao Bin Yang Hongxia |
| |
| Abstract: | Hemoglobin encapsulated in reversed micelles formulated with di-2-ethylhexyl sulfosuccinate (AOT) is found to biocatalyze the polymerization of o-phenylenediamine (o-PDA) with hydrogen peroxide. The resulting polymers with nanometer structure that contain 2,3-phenazine and quinoline have the comparative thermo-stability compared with those obtained through chemical oxidative and enzymatic polymerization. |
| |
| Keywords: | hemoglobin reversed micoemulsions aromatic heterocyclic polymer nano-technology biocatalytic polymerization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
