| 凝胶聚合物电解质MnO2/AC电容器的研究 |
| |
| 引用本文： | 于立娟,张宝宏,杨萍,黄震雷,殷金玲.凝胶聚合物电解质MnO2/AC电容器的研究[J].应用科技,2007,34(1):61-65. |
| |
| 作者姓名： | 于立娟 张宝宏 杨萍 黄震雷 殷金玲 |
| |
| 作者单位： | 哈尔滨工程大学,材料科学与化学工程学院,黑龙江,哈尔滨,150001 |
| |
| 基金项目： | 哈尔滨工程大学校科研和教改项目 |
| |
| 摘 要： | 采用液相氧化法制备了MnO2超级电容器电极材料,以MnO2为正极材料,活性炭(AC)为负极材料,丙烯腈作聚合物单体,碳酸二甲酯(DMC)与碳酸乙烯酯(EC)的混和液作增塑剂,高氯酸锂为支持电解质,采用内聚合法制备PAN基凝胶聚合物电解质MnO2/AC混合电容器.通过循环伏安、交流阻抗、恒流充放电等测试方法对混合电容器的电化学性能进行了测试.结果表明:混合电容器的工作电压为2.5 V,比容量为27.3 F/g(i=0.5 mA/cm2),比同电解质体系的AC/AC电容器提高约48.21%.
|
| 关 键 词： | 二氧化锰 混合电容器 凝胶聚合物电解质 聚丙烯腈 |
| 文章编号： | 1009-671X（2007）01-0061-05 |
| 收稿时间： | 2006-06-23 |
| 修稿时间： | 2006-06-23 |
Research on MnO2/AC capacitor with gel polymer electrolytes |
| |
| YU Li-juan,ZHANG Bao-hong,YANG Ping,HUANG Zhen-lei,YIN Jin-ling.Research on MnO2/AC capacitor with gel polymer electrolytes[J].Applied Science and Technology,2007,34(1):61-65. |
| |
| Authors: | YU Li-juan ZHANG Bao-hong YANG Ping HUANG Zhen-lei YIN Jin-ling |
| |
| Institution: | College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China |
| |
| Abstract: | MnO_2 was synthesized by liquid oxo-process method,and Polyacrylonitrile(PAN) based gel polymer electrolytes MnO_2/AC hybrid capacitors were fabricated by an insitu polymerizational method with MnO_2 as positive electrode and activated carbon as negative electrode.A mixture of dimethyl carbonate(DMC) and ethylene carbonate(EC) was used as a plasticizer.Lithium perchlorate were used as supporting electrolytes.Hybrid capacitor properties were determined by experiments of cyclic voltammetry,impedance spectrum,constant current charge/discharge,showing that the working voltage of hybrid capacitor reaches to 2.5 V.The specific capacitance of the supercapacitor is 27.3 F/g(i=0.5 mA/cm~2) and is 48.21% higher than that of AC/AC capacitor with the same electrolyte. |
| |
| Keywords: | MnO_2 hybrid capacitor gel polymer electrolytes PAN |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
