| 钍(Ⅳ)、铀(Ⅵ)的N_2O_2型Schiff碱配合物的合成与性质 |
| |
| 引用本文： | 王明雄,娄兆文,宋功武,马世安.钍(Ⅳ)、铀(Ⅵ)的N_2O_2型Schiff碱配合物的合成与性质[J].湖北大学学报(自然科学版),1990(3). |
| |
| 作者姓名： | 王明雄 娄兆文 宋功武 马世安 |
| |
| 作者单位： | 湖北大学化学系
(王明雄，娄兆文)，湖北大学实验中心
(宋功武)，湖北大学实验中心(马世安) |
| |
| 摘 要： | 合成了Th(Ⅳ)、U(Ⅵ)与N,N′亚乙基二(2—羟基—3—甲氧基苯甲亚胺)和N,N′-邻亚苯基二(2—羟基—3—甲氧基苯甲亚胺)的四个Schiff碱配合物:ThL_2·XH_2O和UO_2L·H_2O(L=MSEA和MSPA,X=0,2),通过元素分析、摩尔电导、红外光谱、紫外光谱、荧光光谱、x—射线粉末衍射和差热分析,研究了配合物的组成和有关性质。
|
| 关 键 词： | 钍 铀 Schiff碱配合物 |
SYNTHESIS AND PROPERTIES OF COMPLEXES OF Th(IV) ,U(VI) WITH N_2O_2 TYPE SCHIFF BASES |
| |
| Wang Mingxiong Lou Zhaowen Song Gongwu Ma Shi.SYNTHESIS AND PROPERTIES OF COMPLEXES OF Th(IV) ,U(VI) WITH N_2O_2 TYPE SCHIFF BASES[J].Journal of Hubei University(Natural Science Edition),1990(3). |
| |
| Authors: | Wang Mingxiong Lou Zhaowen Song Gongwu Ma Shi |
| |
| Institution: | Wang Mingxiong Lou Zhaowen Song Gongwu Ma Shi
(Depcrtment of Chemistry) (Experimental Center) |
| |
| Abstract: | The solid complexes of thorium (IV ) and dioxouranium (VI) with N, N' - ethyleneMs (3 -methoxysalicylideneimine(H2MSEA) orN, N'-o-phenylenebis (3-methoxysalicylideneirnne)] (H2MSPA) have been prepared .their Conductance, infrared specta, UV spectra, fluorescence spectra. X -ray powder diffraction,differential thermal analysis and the solubility in various solvents have been investigated. The new complexes have the composition of Th L2. XH2O and UO2L. HO (L = MSEA,or MSPA, X = 0,2)respectirely. The molar conductance data indicate that these complexes are characterized as non - electrolytes. |
| |
| Keywords: | Thorium(IV) Dioxouranium(VI) Schiff base complex |
| 本文献已被 CNKI 等数据库收录！ |
|
