The synthesis of a new type of calix[4]arene with chiral pendant |
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Authors: | He Yong-bing Li Jian-feng Meng Ling-zhi Xiao Yuan-jing Yu Tian-xiang Wu Cheng-tai |
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Institution: | (1) College of Chemistry and Molecule Science, Wuhan University, 430072 Wuhan, China |
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Abstract: | Two new chiral calixarenes were synthesized by condensing 1,3-bis-chlorocarbomethyl-calix4] arenes with (1S, 2S)-2-amino-1-(4-nitrophenyl)-1,3-propanediol,
a by-product from antibiotic industry, and were characterized by1H-NMR, MS-FAB, and elemental analysis. The1H-NMR spectra show that those molecules assume a cone conformation in solution.
Foundation item: Supported by the Zi-Qiang Science Foundation of Wuhan University
Biography: He Yong-bing, (1945-), male, Professor, research direction: supramolecular chemistry. |
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Keywords: | Calix[4]arene chirality synthesis conformation |
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